Liquid-crystalline medium

ABSTRACT

The invention relates to a liquid-crystalline medium based on a mixture of polar compounds which contains
         at least one compound of the formula I,       

                         
and
         at least one additional compound,   and to the use of the LC mixtures for an active- or passive matrix addressed displays, in particular based on the VA, PSA, PS-VA, IPS, FFS, PS-IPS, PS-FFS technology, preferably in optical displays for the self-aligning VA mode.

The invention relates to a liquid-crystalline medium for LC displays, especially for displays without any orientation layer, i.e. polyimide layer which contain at least one self-aligning additive.

Media of this type can be used, in particular, for electro-optical displays having active-matrix or passive-matrix addressing based on the ECB effect.

The principle of electrically controlled birefringence, the ECB effect or also DAP (deformation of aligned phases) effect, was described for the first time in 1971 (M. F. Schieckel and K. Fahrenschon, “Deformation of nematic liquid crystals with vertical orientation in electrical fields”, Appl. Phys. Lett. 19 (1971), 3912). This was followed by papers by J. F. Kahn (Appl. Phys. Lett. 20 (1972), 1193) and G. Labrunie and J. Robert (J. Appl. Phys. 44 (1973), 4869).

The papers by J. Robert and F. Clerc (SID 80 Digest Techn. Papers (1980), 30), J. Duchene (Displays 7 (1986), 3) and H. Schad (SID 82 Digest Techn. Papers (1982), 244) showed that liquid-crystalline phases must have high values for the ratio of the elastic constants K₃/K₁, high values for the optical anisotropy Δn and values for the dielectric anisotropy of Δ∈≦−0.5 in order to be suitable for use in high-information display elements based on the ECB effect. Electro-optical display elements based on the ECB effect have a homeotropic edge alignment (VA technology=vertically aligned).

Displays which use the ECB effect, as so-called VAN (vertically aligned nematic) displays, for example in the MVA (multi-domain vertical alignment, for example: Yoshide, H. et al., paper 3.1: “MVA LCD for Notebook or Mobile PCs . . . ”, SID 2004 International Symposium, Digest of Technical Papers, XXXV, Book I, pp. 6 to 9, and Liu, C. T. et al., paper 15.1: “A 46-inch TFT-LCD HDTV Technology . . . ”, SID 2004 International Symposium, Digest of Technical Papers, XXXV, Book II, pp. 750 to 753), PVA (patterned vertical alignment, for example: Kim, Sang Soo, paper 15.4:

“Super PVA Sets New State-of-the-Art for LCD-TV”, SID 2004 International Symposium, Digest of Technical Papers, XXXV, Book II, pp. 760 to 763), ASV (advanced super view, for example: Shigeta, Mitzuhiro and Fukuoka, Hirofumi, paper 15.2: “Development of High Quality LCDTV”, SID 2004 International Symposium, Digest of Technical Papers, XXXV, Book II, pp. 754 to 757) modes, have established themselves as one of the three more recent types of liquid-crystal display that are currently the most important, in particular for television applications, besides IPS (in-plane switching) displays (for example: Yeo, S. D., paper 15.3: “An LC Display for the TV Application”, SID 2004 International Symposium, Digest of Technical Papers, XXXV, Book II, pp. 758 & 759) and the long-known TN (twisted nematic) displays. The technologies are compared in general form, for example, in Souk, Jun, SID Seminar 2004, seminar M-6: “Recent Advances in LCD Technology”, Seminar Lecture Notes, M-6/1 to M-6/26, and Miller, Ian, SID Seminar 2004, seminar M-7: “LCD-Television”, Seminar Lecture Notes, M-7/1 to M-7/32. Although the response times of modern ECB displays have already been significantly improved by addressing methods with overdrive, for example: Kim, Hyeon Kyeong et al., paper 9.1: “A 57-in. Wide UXGA TFT-LCD for HDTV Application”, SID 2004 International Symposium, Digest of Technical Papers, XXXV, Book I, pp. 106 to 109, the achievement of video-compatible response times, in particular on switching of grey shades, is still a problem which has not yet been satisfactorily solved.

Industrial application of this effect in electro-optical display elements requires LC phases, which have to satisfy a multiplicity of requirements. Particularly important here are chemical resistance to moisture, air and physical influences, such as heat, infrared, visible and ultraviolet radiation and direct and alternating electric fields.

Furthermore, industrially usable LC phases are required to have a liquid-crystalline mesophase in a suitable temperature range and low viscosity.

None of the hitherto-disclosed series of compounds having a liquid-crystalline mesophase includes a single compound which meets all these requirements. Mixtures of two to 25, preferably three to 18, compounds are therefore generally prepared in order to obtain substances which can be used as LC phases. However, it has not been possible to prepare optimum phases easily in this way since no liquid-crystal materials having significantly negative dielectric anisotropy and adequate long-term stability were hitherto available.

Matrix liquid-crystal displays (MLC displays) are known. Non-linear elements which can be used for individual switching of the individual pixels are, for example, active elements (i.e. transistors). The term “active matrix” is then used, where a distinction can be made between two types:

-   1. MOS (metal oxide semiconductor) transistors on a silicon wafer as     substrate -   2. thin-film transistors (TFTs) on a glass plate as substrate.

In the case of type 1, the electro-optical effect used is usually dynamic scattering or the guest-host effect. The use of single-crystal silicon as substrate material restricts the display size, since even modular assembly of various part-displays results in problems at the joints.

In the case of the more promising type 2, which is preferred, the electro-optical effect used is usually the TN effect.

A distinction is made between two technologies: TFTs comprising compound semiconductors, such as, for example, CdSe, or TFTs based on polycrystalline or amorphous silicon. The latter technology is being worked on intensively worldwide.

The TFT matrix is applied to the inside of one glass plate of the display, while the other glass plate carries the transparent counterelectrode on its inside. Compared with the size of the pixel electrode, the TFT is very small and has virtually no adverse effect on the image. This technology can also be extended to fully colour-capable displays, in which a mosaic of red, green and blue filters is arranged in such a way that a filter element is opposite each switchable pixel.

The term MLC displays here covers any matrix display with integrated non-linear elements, i.e. besides the active matrix, also displays with passive elements, such as varistors or diodes (MIM=metal-insulator-metal).

MLC displays of this type are particularly suitable for TV applications (for example pocket TVs) or for high-information displays in automobile or air-craft construction. Besides problems regarding the angle dependence of the contrast and the response times, difficulties also arise in MLC displays due to insufficiently high specific resistance of the liquid-crystal mixtures [TOGASHI, S., SEKIGUCHI, K., TANABE, H., YAMAMOTO, E., SORI-MACHI, K., TAJIMA, E., WATANABE, H., SHIMIZU, H., Proc. Eurodisplay 84, September 1984: A 210-288 Matrix LCD Controlled by Double Stage Diode Rings, pp. 141 ff., Paris; STROMER, M., Proc. Eurodisplay 84, September 1984: Design of Thin Film Transistors for Matrix Addressing of Television Liquid Crystal Displays, pp. 145 ff., Paris]. With decreasing resistance, the contrast of an MLC display deteriorates. Since the specific resistance of the liquid-crystal mixture generally drops over the life of an MLC display owing to interaction with the inside surfaces of the display, a high (initial) resistance is very important for displays that have to have acceptable resistance values over a long operating period.

There thus continues to be a great demand for MLC displays having very high specific resistance at the same time as a large working-temperature range, short response times and a low threshold voltage with the aid of which various grey shades can be produced.

The disadvantage of the frequently-used MLC-TN displays is due to their comparatively low contrast, the relatively high viewing-angle dependence and the difficulty of generating grey shades in these displays.

VA displays have significantly better viewing-angle dependencies and are therefore principally used for televisions and monitors. However, there continues to be a need here to improve the response times, in particular with respect to the use of televisions having frame rates (image change frequency/repetition rates) of greater than 60 Hz. At the same time, however, the properties, such as, for example, the low-temperature stability, must not be impaired.

The reliability of liquid crystal (LC) mixtures is one of the major issues in today's LCD industry. A main aspect is the stability of the liquid crystal molecules towards the light emitted from the backlight unit of the LCD. Light induced reactions of the LC material can cause display defects known as image sticking. This strongly reduces the lifetime of the LCD and is one of the main reliability criterions in LCD industry.

For example, liquid crystal mixtures containing LC materials with alkenyl-moieties often show some kind of degradation during long term backlight irradiation. This degradation can be observed by measuring the Voltage Holding Ratio (VHR) of the LC mixtures which have been objected to backlight irradiation for a defined time period.

Also other kinds of irradiation, like the UV-light, necessary for the curing of reactive mesogens (RMs), especially for the PS-VA technology, may lead to a reduction of the VHR values of a test-cell or of a display. The use of cut-filters in order to reduce this effect is of limited applicability. By increasing the wavelength of the curing-light the VHR is improved, but at the same time the reaction speed of the RMs is reduced and this effect does not fit with the requirements of the LCD industry.

Thus, a solution is needed by which the light induced degradation of a LC mixture is strongly reduced. Especially, in terms of LCD performance, there is an interest to use liquid-crystalline compounds containing an alkenyl side chain in order to achieve faster switching times and hence better moving picture performances. Especially since the trend for LCD TC clearly is to go to higher frame rates, e.g. 200 Hz or higher, also including 3D applications.

The invention thus has an object of providing self-aligning additives and liquid-crystal mixtures, in particular for monitor and TV applications, which are based on the ECB effect especially for VA, PSA and PS-VA applications, which do not have the above-mentioned disadvantages or only do so to a reduced extent. In particular, it must be ensured for monitors and televisions that they also operate at extremely high and extremely low temperatures and have short response times and at the same time have improved reliability behaviour, in particular have no or significantly reduced image sticking after long operating times.

In conventional VA-displays a polyimide (Pl) layer is needed for inducing the required homeotropic orientation of the LC. Beside the significant costs due to its production, unfavourable interaction between Pl and LC often leads to a reduction of the electric resistance of the VA-display. The number of useful LC molecules is thus significantly reduced, at the expenses of the overall switching performances (e.g. higher switching times) of the display. Getting rid of Pl is thus desirable, while providing an alternative for the required homeotropic orientation.

It has now been found that these and other objects can be achieved if LC media according to the invention are used in LC displays, especially in displays without any orientation layer (polyimide layer).

LC mixtures which contain at least one compound of the formula I are already known from WO 2014/090362 A1. Contrary to the mixtures of the prior art the LC mixtures of the present invention combines the use of the aligning additive and of relatively large amounts of materials to enhance to clearing temperature by maintaining a good low temperature stability of at least 1000 h at −20° C. so that the mixtures are preferably suitable for outdoor use.

The present invention MAKES it possible to provide such mixtures with high clearing points of preferably >80° C. and good low temperature stability (LTS).

The invention thus relates to a liquid-crystalline medium which contains

-   -   at least one compound of the formula I,

in which

-   R¹ denotes an alkyl or alkoxy radical having 1 to 15 C atoms, where,     in addition, one or more CH₂ groups in these radicals may each be     replaced, independently of one another, by —C≡C—, —CF₂O—, —CH═CH—,

-    —O—, —CO—O—, —O—CO— in such a way that O atoms are not linked     directly to one another, and in which, in addition, one or more H     atoms may be replaced by halogen, -   L¹, L² and L³ each, independently of one another, denote H, F, Cl,     CF₃, CHF₂ or alkyl with 1-5 carbon atoms, preferably F or alkyl, and -   m denotes 0, 1, 2, 3, 4, 5 or 6     and     -   at least one compound selected from the group of compounds of         the formulae IA to I-K,

in which

-   R¹* and R² each, independently of one another, denote an alkyl or     alkoxy radical having 1 to 15 C atoms, where, in addition, one or     more CH₂ groups in these radicals may each be replaced,     independently of one another, by —C≡C—, —CF₂O—, —CH═CH—,

-    —O—CO— in such a way that O atoms are not linked directly to one     another, and in which, in addition, one or more H atoms may be     replaced by halogen, -   a 0 or 1, -   L¹ and L² each, independently of one another, denote H, F, Cl, CF₃     or CHF₂, preferably H or F.

Preferred LC mixtures according to the present invention are characterized by a negative dielectrically anisotropy (Δ∈).

Such kinds of mixtures are highly suitable for the use in displays which do not contain any orientation layer. Liquid crystal display devices, in general have a structure in which a liquid crystal mixture is sealed between a pair of insulating substrates, such as glass substrates, in such a manner that the liquid crystal molecules thereof are orientated in a predetermined direction, and an orientation film is formed on the respective substrates on the side of the liquid crystal mixture. As a material of an orientation film, there is usually used a polyimide (Pl). Homeotropic orientation of the LC molecules is especially necessary for LC modes like PVA, PS-VA, VA, PM (passive matrix)-VA, etc., and can be achieved by the use of self-aligning additives, without the need of an orientation film. The mixtures according to the invention show an improved light and temperature stability compared to LC mixtures without any self-aligning additives.

In a preferred embodiment, the LC mixture according to the invention contains additionally at least one polymerisable compound (also called reactive mesogen (RM)). Such kinds of LC mixtures are highly suitable for Pl-free PS-VA displays. The alignment of the LC molecules is induced by the self-aligning additives and the induced orientation (pre-tilt) may be additionally tuned or stabilized by the polymerization of the RMs, under conditions suitable for a multidomain switching. By the tuning of the UV-curing conditions it is possible in one single step to improve simultaneously switching time and contrast ratio. Reliability of the mixture (VHR) after light stress (both UV-curing and Backlight (BLT)) is improved compared to LC mixtures without any self-aligning additive filled in a “classical” Pl-coated test cell. Furthermore, the UV-curing may be performed by using cut-filters at a wavelength by which the polymerization of the RMs is still reasonably fast and the VHR values are on an acceptable level.

The mixtures according to the invention preferably exhibit very broad nematic phase ranges having clearing points ≧70° C., preferably ≧80° C., in particular ≧90° C., very favourable values for the capacitive threshold, relatively high values for the holding ratio and at the same time very good low-temperature stabilities at −20° C. and −30° C., as well as relatively low rotational viscosities and short response times.

Some preferred embodiments of the mixtures according to the invention are indicated below.

In the compounds of the formulae I R¹ preferably denotes straight-chain alkyl, in particular CH₃, C₂H₅, n-C₃H₇, n-C₄H₉, n-C₅H₁₁, n-C₆H₁₃, furthermore alkenyloxy, in particular OCH₂CH═CH₂, OCH₂CH═CHCH₃, OCH₂CH═CHC₂H₅, alkoxy, in particular OC₂H₅, OC₃H₇, OC₄H₉, OC₅H₁₁ and OC₆H₁₃.

In the compounds of the formula I L¹, L² and L³ are each independently preferably H or F or alkyl with 1-5 carbon atoms. In the compounds of the formula I L¹, L² and L³ denotes most preferably H.

m is preferably 0 or 1.

Preferred compounds of the formula I are the compounds of the sub-formulae I-1 to I-36,

in which R¹ has the meanings given in Claim 1, preferably denotes a straight-chain alkyl radical having 1-7 C atoms.

The mixture according to the invention very particularly contains at least one self-aligning additive selected from the following group of compounds of the sub-formulae

in which alkyl denotes a straight-chain alkyl radical having 1 to 7 carbon atoms, preferably C₂H₅, n-C₃H₇, n-C₄H₉, n-C₅H₁₁, n-C₆H₁₃ or n-C₇H₁₅, most preferably n-C₃H₇.

Especially preferred mixtures contain a compound of the formula I-2a-1

The compounds of the formula I can be prepared by methods known per se, which are described in standard works for organic chemistry as such, for example, Houben-Weyl, Methoden der organischen Chemie, Thieme-Verlag, Stuttgart.

The compounds of the formula I can be prepared for example as follows:

The media according to the invention preferably contain one, two, three, four or more, preferably one, self-aligning additive, preferably selected from the compounds of the formulae I-1 to I-36.

The self-aligning additives of the formula I are preferably employed in the liquid-crystalline medium in amounts of ≧0.01% by weight, preferably 0.1-10% by weight, based on the mixture as a whole. Particular preference is given to liquid-crystalline media which contain 0.1-5%, preferably 0.1-4%, by weight of one or more self-aligning additives, based on the total mixture, especially additives which are selected from the group of compounds of the formula I-1 to I-36.

The use of preferably 2.5 to 5% by weight of the compounds of the formula I results in a complete homeotropic alignment of the LC layer for conventional LC thickness (3 to 4 μm) and for the substrate materials used in the display industry. Special surface treatment may allow to significantly reduce the amount of the compound(s) of the formula I which means less than 2.5% by weight.

Preferred compounds of the formulae I-A to I-K are the compounds of the formula

in which alkyl and alkyl* each, independently of one another, denote a straight-chain alkyl radical having 1-6 C atoms, alkoxy or O-alkyl denotes a straight-chain alkoxy radical having 1-6 C atoms and L¹ and L² each, independently of one another, denote H, F, Cl, CF₃ or CHF₂, preferably H or F.

In particular, the following compounds of the formula I-A are preferred

wherein alkyl, alkyl* and alkoxy have the meanings indicated above.

Preferred sub-formulae of the formula I-A are the compounds of the formula I-A-2a, I-A-4a, I-A-6a and I-A-7a.

Preferred mixtures contain at least one compound of the formula I-A-2a and/or at least one compound of the formula I-A-4a.

Preferred mixtures contain at least one compound of the formula IA-4a and at least one compound of the formula I-A-7a.

Preferred mixtures contain at least one compound of the formula I-A-2a and at least one compound of the formula I-A-4a and at least one compound of the formula I-A-7a.

Especially preferred mixtures contain at least one compound of the formula IA-2a and at least one compound of the formula I-A-4a.

Especially preferred mixtures contain at least one compound of the formula I-A-2a and at least one compound of the formula I-A-4a and at least one compound of the formula I-B-1.

The media according to the invention preferably comprise one, two, three, four or more, preferably one, two or three, compounds of the formula I.

The media according to the invention preferably comprise one, two, three, four or more, preferably one, two or three, compounds of the formulae I-A.

The media according to the invention preferably comprise one, two, three, four or more, preferably one or two compounds of the formula I-B.

The compounds of the formula I-A are preferably employed in the liquid crystalline medium in amounts of 5-60% by weight, preferably 10-60% by weight, based on the mixture as a whole. The compounds of the formula IB are preferably employed in the liquid crystalline medium in amounts of 0-35% by weight, preferably 2-25% by weight, based on the mixture as a whole. The compounds of the formula I-A and I-B are preferably employed in the liquid crystalline medium in amounts of ≧20% by weight, preferably 25-60% by weight, in particular 30-60% by weight, based on the mixture as a whole.

The compounds of the formula I-C to I-I are preferably employed in the liquid crystalline medium in amounts of 0.5-25% by weight, preferably 5-20% by weight, based on the mixture as a whole.

Preferred embodiments of the liquid-crystalline medium according to the invention are indicated below:

-   a) Liquid-crystalline medium which additionally comprises one or     more compounds selected from the group of the compounds of the     formulae IIA, IIB and IIC:

-   -   in which     -   R^(2A), R^(2B) and R^(2C) each, independently of one another,         denote H, an alkyl or alkenyl radical having up to 15 C atoms         which is unsubstituted, monosubstituted by CN or CF₃ or at least         monosubstituted by halogen, where, in addition, one or more CH₂         groups in these radicals may be replaced by —O—, —S—,

-   -    —C≡C—, —CF₂O—, —OCF₂—, —OC—O— or —O—CO— in such a way that O         atoms are not linked directly to one another,     -   L¹⁻⁴ each, independently of one another, denote F, Cl, CF₃ or         CHF₂,     -   Z² and Z^(2′) each, independently of one another, denote a         single bond, —CH₂CH₂—, —CH═CH—, —CF₂O—, —OCF₂—, —CH₂O—, —OCH₂—,         —COO—, —OCO—, —C₂F₄—, —CF═CF—, —CH═CHCH₂O—,     -   p denotes 0, 1 or 2,     -   q denotes 0 or 1, and     -   v denotes 1 to 6.     -   In the compounds of the formulae IIA and IIB, Z² may have         identical or different meanings. In the compounds of the formula         IIB, Z² and Z^(2′) may have identical or different meanings.     -   In the compounds of the formulae IIA, IIB and IIC, R^(2A),         R^(2B) and R^(2C) each preferably denote alkyl having 1-6 C         atoms, in particular CH₃, C₂H₅, n-C₃H₇, n-C₄H₉, n-C₅H₁₁.     -   In the compounds of the formulae IIA and IIB, L¹, L², L³ and L⁴         preferably denote L¹=L²=F and L³=L⁴=F, furthermore L¹=F and         L²=Cl, L¹=Cl and L²=F, L³=F and L⁴=Cl, L³=Cl and L⁴=F. Z² and         Z^(2′) in the formulae IIA and IIB preferably each,         independently of one another, denote a single bond, furthermore         a —C₂H₄— or —CH₂O— bridge.     -   If in the formula IIB Z²═—C₂H₄— or —CH₂O—, Z^(2′) is preferably         a single bond or, if Z^(2′)=—C₂H₄— or —CH₂O—, Z² is preferably a         single bond. In the compounds of the formulae IIA and IIB,         (O)C_(v)H_(2v+1) preferably denotes OC_(v)H_(2v+1), furthermore         C_(v)H_(2v+1). In the compounds of the formula IIC,         (O)C_(v)H_(2v+1) preferably denotes C_(v)H₂v+1. In the compounds         of the formula IIC, L³ and L⁴ preferably each denote F.     -   Preferred compounds of the formulae IIA, IIB and IIC are         indicated below:

-   -   in which alkyl and alkyl* each, independently of one another,         denote a straight-chain alkyl radical having 1-6 C atoms and in         which alkenyl and alkenyl* each, independently of one another,         denote a straight-chain alkenyl radical having 2-6 C atoms.     -   Particularly preferred mixtures according to the invention         comprise one or more compounds of the formulae IIA-2, IIA-8,         IIA-14, IIA-29, IIA-35, IIA-74, IIB-2, IIB-11, IIB-16 and IIC-1.     -   The proportion of compounds of the formulae IIA and/or IIB in         the mixture as a whole is preferably at least 10% by weight.     -   Particularly preferred media according to the invention comprise         at least one compound of the formula IIC-1,

-   -   in which alkyl and alkyl* have the meanings indicated above,         preferably in amounts of ≧3% by weight, in particular ≧5% by         weight and particularly preferably 5-25% by weight.

-   b) Liquid-crystalline medium which additionally comprises one or     more compounds of the formula III,

-   -   in which     -   R³¹ and R³² each, independently of one another, denote a         straight-chain alkyl, alkoxyalkyl, alkenyl or alkoxy radical         having up to 12 C atoms, and

-   -   Z³ denotes a single bond, —CH₂CH₂—, —CH═CH—, —CF₂O—, —OCF₂—,         —CH₂O—, —OCH₂—, —COO—, —OCO—, —C₂F₄—, —C₄H₈—, —CF═CF—.     -   Preferred compounds of the formula III are indicated below:

-   -   alkyl and     -   alkyl* each, independently of one another, denote a         straight-chain alkyl radical having 1-6 C atoms.     -   The medium according to the invention preferably comprises at         least one compound of the formula IIIa and/or formula IIIb.     -   The proportion of compounds of the formula III in the mixture as         a whole is preferably at least 5% by weight.

-   c) Liquid-crystalline medium additionally comprising a compound of     the formula

-   -   preferably in total amounts of ≧5% by weight, in particular ≧10%         by weight.     -   Preference is given to mixtures according to the invention         comprising the compound

-   -   Preference is furthermore given to mixtures according to the         invention comprising the compound

-   d) Liquid-crystalline medium which additionally comprises one or     more tetracyclic compounds of the formulae

-   -   in which     -   R⁷⁻¹⁰ each, independently of one another, have one of the         meanings indicated for R^(2A) in Claim 5, and     -   w and x each, independently of one another, denote 1 to 6.     -   Particular preference is given to mixtures comprising at least         one compound of the formula V-8.

-   e) Liquid-crystalline medium which additionally comprises one or     more compounds of the formulae Y-1 to Y-6,

-   -   in which R¹⁴-R¹⁹ each, independently of one another, denote an         alkyl or alkoxy radical having 1-6 C atoms; z and m each,         independently of one another, denote 1-6; x denotes 0, 1, 2 or         3.     -   The medium according to the invention particularly preferably         comprises one or more compounds of the formulae Y-1 to Y-6,         preferably in amounts of ≧5% by weight.

-   f) Liquid-crystalline medium additionally comprising one or more     fluorinated terphenyls of the formulae T-1 to T-21,

-   -   in which     -   R denotes a straight-chain alkyl or alkoxy radical having 1-7 C         atoms, and m=0, 1, 2, 3, 4, 5 or 6 and n denotes 0, 1, 2, 3 or         4.     -   R preferably denotes methyl, ethyl, propyl, butyl, pentyl,         hexyl, methoxy, ethoxy, propoxy, butoxy, pentoxy.     -   The medium according to the invention preferably comprises the         terphenyls of the formulae T-1 to T-21 in amounts of 2-30% by         weight, in particular 5-20% by weight.     -   Particular preference is given to compounds of the formulae T-1,         T-2, T-20 and T-21. In these compounds, R preferably denotes         alkyl, furthermore alkoxy, each having 1-5 C atoms. In the         compounds of the formula T-20, R preferably denotes alkyl or         alkenyl, in particular alkyl. In the compound of the formula         T-21, R preferably denotes alkyl.     -   The terphenyls are preferably employed in the mixtures according         to the invention if the Δn value of the mixture is to be ≧0.1.         Preferred mixtures comprise 2-20% by weight of one or more         terphenyl compounds selected from the group of the compounds T-1         to T-21.

-   g) Liquid-crystalline medium additionally comprising one or more     biphenyls of the formulae B-1 to B-3,

-   -   in which     -   alkyl and alkyl* each, independently of one another, denote a         straight-chain alkyl radical having 1-6 C atoms, and     -   alkenyl and alkenyl* each, independently of one another, denote         a straight-chain alkenyl radical having 2-6 C atoms.     -   The proportion of the biphenyls of the formulae B-1 to B-3 in         the mixture as a whole is preferably at least 3% by weight, in         particular ≧5% by weight.     -   Of the compounds of the formulae B-1 to B-3, the compounds of         the formula B-2 are particularly preferred.     -   Particularly preferred biphenyls are

-   -   in which alkyl* denotes an alkyl radical having 1-6 C atoms. The         medium according to the invention particularly preferably         comprises one or more compounds of the formulae B-1a and/or         B-2c.

-   h) Liquid-crystalline medium comprising at least one compound of the     formulae Z-1 to Z-7,

-   -   in which R and alkyl have the meanings indicated above.

-   i) Liquid-crystalline medium comprising at least one compound of the     formulae O-1 to O-11,

-   -    in which R¹ and R² have the meanings indicated for R^(2A). R¹         and R² preferably each, independently of one another, denote         straight-chain alkyl or Alkenyl having up to 6 carbon atoms.     -   Mixtures according to the invention very particularly preferably         comprise the compounds of the formula O-5, O-7, O-9, O-10 and/or         O-11, in particular in amounts of 5-30%.     -   Preferred compounds of the formulae O-5 and O-10 are indicated         below:

-   -   The medium according to the invention particularly preferably         comprises the tricyclic compounds of the formula O-10a and/or of         the formula O-10b in combination with one or more bicyclic         compounds of the formulae O-10a to O-10d. The total proportion         of the compounds of the formulae O-5a and/or O-5b in combination         with one or more compounds selected from the bicyclic compounds         of the formulae O-10a to O-10d is 5-40%, very particularly         preferably 15-35%.     -   Very particularly preferred mixtures comprise compounds O-5a and         O-10a:

-   -   Compounds O-5a and O-10a are preferably present in the mixture         in a concentration of 15-35%, particularly preferably 15-25% and         especially preferably 18-22%, based on the mixture as a whole.

Very particularly preferred mixtures comprise compounds O-5b and O-10a:

-   -   Compounds O-5b and O-10a are preferably present in the mixture         in a concentration of 15-35%, particularly preferably 15-25% and         especially preferably 18-22%, based on the mixture as a whole.     -   Very particularly preferred mixtures comprise the following         three compounds:

-   -   Compounds O-5a, O-5b and O-10a are preferably present in the         mixture in a concentration of 15-35%, particularly preferably         15-25% and especially preferably 18-22%, based on the mixture as         a whole.

-   j) Preferred liquid-crystalline media according to the invention     comprise one or more substances which contain a tetrahydronaphthyl     or naphthyl unit, such as, for example, the compounds of the     formulae N-1 to N-5,

-   -   in which R^(1N) and R^(2N) each, independently of one another,         have the meanings indicated for R^(2A) in Claim 5, preferably         denote straight-chain alkyl, straight-chain alkoxy or         straight-chain alkenyl, and     -   Z¹ and Z² each, independently of one another, denote —C₂H₄—,         —CH═CH—, —(CH₂)₄—, —(CH₂)₃O—, —O(CH₂)₃—, —CH═CHCH₂CH₂—,         —CH₂CH₂CH═CH—, —CH₂O—, —OCH₂—, —COO—, —OCO—, —C₂F₄—, —CF═CF—,         —CF═CH—, —CH═CF—, —CF₂O—, —OCF₂—, —CH₂— or a single bond.

-   k) Preferred mixtures comprise one or more compounds selected from     the group of the difluorodibenzochromane compounds of the formula     BC, chromans of the formula CR, fluorinated phenanthrenes of the     formulae PH-1 and PH-2, fluorinated dibenzofurans of the formula     BF-1 and BF-2 and fluorinated dibenzothiophene compounds of the     formula BS-1 and BS-2,

-   -   in which     -   R^(B1), R^(B2), R^(CR1), R^(CR2), R¹, R² each, independently of         one another, have the meaning of R^(2A). c denotes 0, 1 or 2 and         d denotes 1 or 2.     -   The mixtures according to the invention preferably comprise the         compounds of the formulae BC, CR, PH-1, PH-2, BF-1, BF-2, BS-1         and/or BS-2 in amounts of 3 to 20% by weight, in particular in         amounts of 3 to 15% by weight.     -   Particularly preferred compounds of the formulae BC, CR, BF-1         are the compounds BC-1 to BC-7 and CR-1 to CR-5,

-   -   in which     -   alkyl and alkyl* each, independently of one another, denote a         straight-chain alkyl radical having 1-6 C atoms, and alkenyl and     -   alkenyl* each, independently of one another, denote a         straight-chain alkenyl radical having 2-6 C atoms.

-   l) Preferred mixtures comprise one or more indane compounds of the     formula In,

-   -   in which     -   R¹¹, R¹²,     -   R¹³ each, independently of one another, denote a straight-chain         alkyl, alkoxy, alkoxyalkyl or alkenyl radical having 1-6 C         atoms,     -   R¹² and R¹³ additionally denote H or halogen,

-   -   i denotes 0, 1 or 2.     -   In the case that R¹² and/or R¹³ denote halogen, halogen is         preferably F.     -   Preferred compounds of the formula In are the compounds of the         formulae In-1 to In-16 indicated below:

-   -   Particular preference is given to the compounds of the formulae         In-1, In-2, In-3 and In-4.     -   The compounds of the formula In and the sub-formulae In-1 to         In-16 are preferably employed in the mixtures according to the         invention in concentrations ≧5% by weight, in particular 5-30%         by weight and very particularly preferably 5-25% by weight.

-   m) Preferred mixtures additionally comprise one or more compounds of     the formulae L-1 to L-11,

-   -   in which     -   R, R¹ and R² each, independently of one another, have the         meanings indicated for R^(2A) in Claim 5, and alkyl denotes an         alkyl radical having 1-6 C atoms. s denotes 1 or 2.     -   Particular preference is given to the compounds of the formulae         L-1 and L-4, in particular L-4.     -   The compounds of the formulae L-1 to L-11 are preferably         employed in concentrations of 5-50% by weight, in particular         5-40% by weight and very particularly preferably 10-40% by         weight.     -   Preferred mixtures having negative dielectric anisotropy contain         at least one compound of the formula P,

-   -   wherein R¹ has the meanings given for formula I in Claim 1. In a         preferred embodiment R¹ denotes alkyl, in particular n-C₃H₇. The         compound P is preferably used in amounts of 0.01-10%, in         particular 0.01-5%, by weight.

Preference in particular is given to mixtures according to the invention which comprise the following mixture concepts (the acronyms used are explained in Table A. n and m, each independently of one another denote 1-6):

The mixture according to the invention preferably contains

-   -   at least one self-aligning additive of the formula I-2a-1,

preferably in amounts of 0.1-10 wt. %, in particular 2.5-5 wt. %, and/or

-   -   PTP-nOmFF and CPTP-nOmFF and PPTUI-n-m,         and/or     -   PTP-nOmFF and CPTP-nOmFF and PPTUI-n-m and CC-n-V,         and/or     -   PTP-nOmFF and CPTP-nOmFF and CPTP-nm,         and/or     -   Y-nO-Om, PTP-nOmFF and CPTP-nOmFF,         and/or     -   PTP-nOmFF and CPTP-nOmFF and CCPC-nm,         and/or     -   CY-nOm and/or PY-n-Om, CCY-nOm, CPY-n-Om and CCPC-nm and/or         CH-nm and/or CP-nm,         and/or     -   CY-nOm and/or PY-n-Om and PTP-nOmFF and/or CPTP-nOmFF,         and/or     -   CY-nOm and/or and PPTUI-n-m and PTP-nOmFF and/or CPTP-nOmFF,         and/or     -   CY-nOm and/or and PPTUI-n-m and PTP-nOmFF and/or CPTP-nOmFF and         CCPC-nm and/or CH-nm,         and/or     -   CY-nOm and CCOC-n-m and/or CCPC-nm,         and/or     -   CY-nOm and CPYP-n-m,         and/or     -   D-nOmFF and PPT-nOmFF and/or CPTP-nOmFF         and/or     -   D-nOmFF and PPT-nOm and/or CPTP-nOm and/or CCPC-nm,         and/or     -   D-nOmFF and CP-nOmFF and/or PPT-nOm and/or CPTP-nOm and/or         CCPC-nm,     -   D-nOmFF and CP-nOmFF and/or PPT-nOm and/or CPTP-nOm and/or         CBC-nm(F),         and/or     -   CPY-n-Om, in particular CPY-2-O2, CPY-3-O2 and/or CPY-5-O2,         preferably in concentrations >5%, in particular 10-30%, based on         the mixture as a whole,         and/or     -   CY-n-Om, preferably CY-3-O2, CY-3-O4, CY-5-O2 and/or CY-5-O4,         preferably in concentrations >5%, in particular 15-50%, based on         the mixture as a whole,         and/or     -   CCY-n-Om, preferably CCY-4-O2, CCY-3-O2, CCY-3-O3, CCY-3-O1         and/or CCY-5-O2, preferably in concentrations >5%, in particular         10-30%, based on the mixture as a whole,         and/or     -   CLY-n-Om, preferably CLY-2-O4, CLY-3-O2 and/or CLY-3-O3,         preferably in concentrations >5%, in particular 10-30%, based on         the mixture as a whole,         and/or     -   CPY-n-Om and CY-n-Om, preferably in concentrations of 10-80%,         based on the mixture as a whole,         and/or     -   CPY-n-Om and CK-n-F, preferably in concentrations of 10-70%,         based on the mixture as a whole,         and/or     -   CPY-n-Om and CLY-n-Om, preferably in concentrations of 10-80%,         based on the mixture as a whole.         and/or     -   PYP-n-m, preferably one, two or three compounds, preferably in         concentrations of 1-20% of the mixture as a whole.         and/or     -   PY-n-Om, preferably one, two or three compounds, preferably in         concentrations of 1-20% of the mixture as a whole.         and/or     -   PTP-nOmFF, in particular PTP-3O2FF and PTP-5O2FF, preferably in         concentrations >5%, in particular 10-30%, based on the mixture         as a whole,         and/or     -   CPTP-nOmFF, in particular CPTP-3O2FF and CPTP-5O2FF, preferably         in concentrations >10%, in particular 15-50%, based on the         mixture as a whole,         and/or     -   PPTUI-n-m, in particular PPTUI-3-2 and PPTUI-3-4, preferably in         concentrations >10%, in particular 15-50%, based on the mixture         as a whole,         and/or     -   Y-nO-Om, in particular Y-4O-O4, preferably in         concentrations >3%, in particular 5-15%, based on the mixture as         a whole,         and/or     -   CCPC-nm, in particular CCPC-33, CCPC-34, CCPC-35, preferably in         concentrations >3%, in particular 5-15%, based on the mixture as         a whole,         and/or     -   CH-nm, in particular CH-33, CH-35, CH-43 and CH-45, preferably         in concentrations >3%, in particular 5-15%, based on the mixture         as a whole.

The invention furthermore relates to an electro-optical display, preferably a Pl-free display, having active or passive-matrix addressing based on the ECB, VA, PS-VA, PSA, characterised in that it contains, as dielectric, a liquid-crystalline medium according to one or more of Claims 1 to 15.

The liquid-crystalline medium according to the invention preferably has a nematic phase from ≦−20° C. to ≧70° C., particularly preferably from ≦−30° C. to ≧80° C., very particularly preferably from ≦−40° C. to ≧110° C.

The expression “have a nematic phase” here means on the one hand that no smectic phase and no crystallisation are observed at low temperatures at the corresponding temperature and on the other hand that clearing still does not occur on heating from the nematic phase. The investigation at low temperatures is carried out in a flow viscometer at the corresponding temperature and checked by storage in test cells having a layer thickness corresponding to the electro-optical use for at least 100 hours. If the storage stability at a temperature of −20° C. in a corresponding test cell is 1000 h or more, the medium is referred to as stable at this temperature. At temperatures of −30° C. and −40° C., the corresponding times are 500 h and 250 h respectively. At high temperatures, the clearing point is measured by conventional methods in capillaries.

The liquid-crystal mixture preferably has a nematic phase range of at least 60 K and a flow viscosity ν₂₀ of at most 30 mm²·s⁻¹ at 20° C.

The values of the birefringence Δn in the liquid-crystal mixture are generally between 0.07 and 0.26, preferably between 0.09 and 0.20.

The liquid-crystal mixture according to the invention has a Δ∈ of −0.5 to −8.0, in particular −2.5 to −6.0, where Δ∈ denotes the dielectric anisotropy.

The rotational viscosity γ₁ at 20° C. is preferably ≦200 mPa·s, in particular ≦150 mPa·s.

The liquid-crystal media according to the invention have relatively low values for the threshold voltage (V₀). They are preferably in the range from 1.7 V to 3.0 V, particularly preferably ≦2.5 V and very particularly preferably ≦2.3 V.

For the present invention, the term “threshold voltage” relates to the capacitive threshold (V₀), also known as the Freedericks threshold, unless explicitly indicated otherwise.

In addition, the liquid-crystal media according to the invention have high values for the voltage holding ratio in liquid-crystal cells.

For the present invention, the term “dielectrically positive compounds” denotes compounds having a Δ∈>1.5, the term “dielectrically neutral compounds” denotes those having −1.5≦Δ∈<−1.5 and the term “dielectrically negative compounds” denotes those having Δ∈<−1.5. The dielectric anisotropy of the compounds is determined here by dissolving 10% of the compounds in a liquid-crystalline host and determining the capacitance of the resultant mixture in at least one test cell in each case having a layer thickness of 20 μm with homeotropic and with homogeneous surface alignment at 1 kHz. The measurement voltage is typically 0.5 V to 1.0 V, but is always lower than the capacitive threshold of the respective liquid-crystal mixture investigated.

All temperature values indicated for the present invention are in ° C.

The mixtures according to the invention are suitable for all VA-applications, such as, for example, VAN, MVA, (S)-PVA, ASV, PSA (polymer sustained VA) and PS-VA (polymer stabilized VA), preferably for Passive Matrix (PM) Addressing, but are also suitable for Active Matrix Addressing.

The nematic liquid-crystal mixtures in the displays according to the invention generally comprise two components A and B, which themselves consist of one or more individual compounds.

Component A has significantly negative dielectric anisotropy and gives the nematic phase a dielectric anisotropy of ≦−0.5. Preferably component A comprises the compounds of the formulae IIA, IIB and/or IIC, furthermore compounds of the formula III.

The proportion of component A is preferably between 45 and 100%, in particular between 60 and 100%.

For component A, one (or more) individual compound(s) which has (have) a value of Δ∈≦−0.8 is (are) preferably selected. This value must be more negative, the smaller the proportion A in the mixture as a whole.

Component B has pronounced nematogeneity and a flow viscosity of not greater than 30 mm²·s⁻¹, preferably not greater than 25 mm²·s⁻¹, at 20° C.

Particularly preferred individual compounds in component B are extremely low-viscosity nematic liquid crystals having a flow viscosity of not greater than 18 mm²·s⁻¹, preferably not greater than 12 mm²·s⁻¹, at 20° C.

Component B is monotropically or enantiotropically nematic, has no smectic phases and is able to prevent the occurrence of smectic phases down to very low temperatures in liquid-crystal mixtures. For example, if various materials of high nematogeneity are added to a smectic liquid-crystal mixture, the nematogeneity of these materials can be compared through the degree of suppression of smectic phases that is achieved.

The mixture may optionally also comprise a component C, comprising compounds having a dielectric anisotropy of Δ∈≧21.5. These so-called positive compounds are generally present in a mixture of negative dielectric anisotropy in amounts of ≦20% by weight, based on the mixture as a whole.

A multiplicity of suitable materials is known to the person skilled in the art from the literature. Particular preference is given to compounds of the formula III.

In addition, these liquid-crystal phases may also comprise more than 18 components, preferably 18 to 25 components.

The mixtures according to the invention contain one or more compounds of the formula I and one or more compounds of the formula I-A to I-K and preferably contain 4 to 15, in particular 5 to 12, and particularly preferably <10, compounds of the formulae IIA, IIB and/or IIC and optionally III.

Besides compounds of the formula I and at least one compound selected from the group of compounds of the formulae I-A to I-K and the compounds of the formulae IIA, IIB and/or IIC and optionally III, other constituents may also be present, for example in an amount of up to 45% of the mixture as a whole, but preferably up to 35%, in particular up to 10%.

The other constituents are preferably selected from nematic or nematogenic substances, in particular known substances, from the classes of the azoxybenzenes, benzylideneanilines, biphenyls, terphenyls, phenyl or cyclohexyl benzoates, phenyl or cyclohexyl cyclohexanecarboxylates, phenylcyclohexanes, cyclohexylbiphenyls, cyclohexylcyclohexanes, cyclohexylnaphthalenes, 1,4-biscyclohexylbiphenyls or cyclohexylpyrimidines, phenyl- or cyclohexyldioxanes, optionally halogenated stilbenes, benzyl phenyl ethers, tolans and substituted cinnamic acid esters.

The most important compounds which are suitable as constituents of liquid-crystal phases of this type can be characterised by the formula IV R²⁰-L-G-E-R²¹  IV in which L and E each denote a carbo- or heterocyclic ring system from the group formed by 1,4-disubstituted benzene and cyclohexane rings, 4,4′-disubstituted biphenyl, phenylcyclohexane and cyclohexylcyclohexane systems, 2,5-disubstituted pyrimidine and 1,3-dioxane rings, 2,6-disubstituted naphthalene, di- and tetrahydronaphthalene, quinazoline and tetrahydroquinazoline,

G denotes —CH═CH— —N(O)═N— —CH═CQ- —CH═N(O)— —O≡C— —CH₂—CH₂— —CO—O— —CH₂—O— —CO—S— —CH₂—S— —CH═N— —COO-Phe-COO— —CF₂O— —CF═CF— —OCF₂— —OCH₂— —(CH₂)₄— —(CH₂)₃O— or a C—C single bond, Q denotes halogen, preferably chlorine, or —CN, and R²⁰ and R²¹ each denote alkyl, alkenyl, alkoxy, alkoxyalkyl or alkoxycarbonyloxy having up to 18, preferably up to 8, carbon atoms, or one of these radicals alternatively denotes CN, NC, NO₂, NCS, CF₃, SF₅, OCF₃, F, Cl or Br.

In most of these compounds, R²⁰ and R²¹ are different from one another, one of these radicals usually being an alkyl or alkoxy group. Other variants of the proposed substituents are also common. Many such substances or also mixtures thereof are commercially available. All these substances can be prepared by methods known from the literature.

It goes without saying for the person skilled in the art that the VA mixture according to the invention may also comprise compounds in which, for example, H, N, O, Cl and F have been replaced by the corresponding isotopes.

Polymerisable compounds, so-called reactive mesogens (RMs), for example as disclosed in U.S. Pat. No. 6,861,107, may furthermore be added to the mixtures according to the invention in concentrations of preferably 0.12-5% by weight, particularly preferably 0.2-2% by weight, based on the mixture. These mixtures may optionally also comprise an initiator, as described, for example, in U.S. Pat. No. 6,781,665. The initiator, for example Irganox-1076 from Ciba, is preferably added to the mixture comprising polymerisable compounds in amounts of 0-1%. Mixtures of this type can be used for so-called polymer-stabilised VA modes (PS-VA) or PSA (polymer sustained VA), in which polymerisation of the reactive mesogens is intended to take place in the liquid-crystalline mixture. The prerequisite for this is that the liquid-crystal mixture does not itself comprise any polymerisable components.

In a preferred embodiment of the invention, the polymerisable compounds are selected from the compounds of the formula M, R^(Ma)-A^(M1)-(Z^(M1)-A^(M2))_(m1)-R^(Mb)  M in which the individual radicals have the following meanings:

-   R^(Ma) and R^(Mb) each, independently of one another, denote P,     P-Sp-, H, halogen, SF₅, NO₂, an alkyl, alkenyl or alkynyl group,     where at least one of the radicals R^(Ma) and R^(Mb) preferably     denotes or contains a group P or P-Sp-, -   P denotes a polymerisable group, -   Sp denotes a spacer group or a single bond, -   A^(M1) and A^(M2) each, independently of one another, denote an     aromatic, heteroaromatic, alicyclic or heterocyclic group,     preferably having 4 to 25 ring atoms, preferably C atoms, which may     also encompass or contain fused rings, and which may optionally be     mono- or polysubstituted by L, -   L denotes P, P-Sp-, OH, CH₂OH, F, Cl, Br, I, —CN, —NO₂, —NCO, —NCS,     —OCN, —SCN, —C(═O)N(R^(x))₂, —C(═O)Y¹, —C(═O)R^(x), —N(R^(x))₂,     optionally substituted silyl, optionally substituted aryl having 6     to 20 C atoms, or straight-chain or branched alkyl, alkoxy,     alkylcarbonyl, alkoxycarbonyl, alkylcarbonyloxy or alkoxycarbonyloxy     having 1 to 25 C atoms, in which, in addition, one or more H atoms     may be replaced by F, Cl, P or P-Sp-, preferably P, P-Sp-, H, OH,     CH₂OH, halogen, SF₅, NO₂, an alkyl, alkenyl or alkynyl group, -   Y¹ denotes halogen, -   Z^(M1) denotes —O—, —S—, —CO—, —CO—O—, —OCO—, —O—CO—O—, —OCH₂—,     —CH₂O—, —SCH₂—, —CH₂S—, —CF₂O—, —OCF₂—, —CF₂S—, —SCF₂—,     —(CH₂)_(n1)—, —CF₂CH₂—, —CH₂CF₂—, —(CF₂)_(n1)—, —CH═CH—, —CF═CF—,     —C≡C—, —CH═CH—, —COO—, —OCO—CH═CH—, CR⁰R⁰⁰ or a single bond, -   R⁰ and R⁰⁰ each, independently of one another, denote H or alkyl     having 1 to 12 C atoms, -   R^(x) denotes P, P-Sp-, H, halogen, straight-chain, branched or     cyclic alkyl having 1 to 25 C atoms, in which, in addition, one or     more non-adjacent CH₂ groups may be replaced by —O—, —S—, —CO—,     —CO—O—, —O—CO—, —O—CO—O— in such a way that O and/or S atoms are not     linked directly to one another, and in which, in addition, one or     more H atoms may be replaced by F, Cl, P or P-Sp-, an optionally     substituted aryl or aryloxy group having 6 to 40 C atoms, or an     optionally substituted heteroaryl or heteroaryloxy group having 2 to     40 C atoms, -   m1 denotes 0, 1, 2, 3 or 4, and -   n1 denotes 1, 2, 3 or 4,     where at least one, preferably one, two or three, particularly     preferably one or two, from the group R^(Ma), R^(Mb) and the     substituents L present denotes a group P or P-Sp- or contains at     least one group P or P-Sp-.

Particularly preferred compounds of the formula M are those in which

-   R^(Ma) and R^(Mb) each, independently of one another, denote P,     P-Sp-, H, F, Cl, Br, I, —CN, —NO₂, —NCO, —NCS, —OCN, —SCN, SF₅ or     straight-chain or branched alkyl having 1 to 25 C atoms, in which,     in addition, one or more non-adjacent CH₂ groups may each be     replaced, independently of one another, by —C(R⁰)═C(R⁰⁰)—, —C≡C—,     —N(R⁰⁰)—, —O—, —S—, —CO—, —CO—O—, —O—CO—, —O—CO—O— in such a way     that O and/or S atoms are not linked directly to one another, and in     which, in addition, one or more H atoms may be replaced by F, Cl,     Br, I, CN, P or P-Sp-, where at least one of the radicals R^(Ma) and     R^(Mb) preferably denotes or contains a group P or P-Sp-, -   A^(M1) and A^(M2) each, independently of one another, denote     1,4-phenylene, naphthalene-1,4-diyl, naphthalene-2,6-diyl,     phenanthrene-2,7-diyl, anthracene-2,7-diyl, fluorene-2,7-diyl,     coumarine, flavone, where, in addition, one or more CH groups in     these groups may be replaced by N, cyclohexane-1,4-diyl, in which,     in addition, one or more non-adjacent CH₂ groups may be replaced by     O and/or S, 1,4-cyclohexenylene, bicyclo[1.1.1]-pentane-1,3-diyl,     bicyclo[2.2.2]octane-1,4-diyl, spiro[3.3]heptane-2,6-diyl,     piperidine-1,4-diyl, decahydronaphthalene-2,6-diyl,     1,2,3,4-tetrahydronaphthalene-2,6-diyl, indane-2,5-diyl or     octahydro-4,7-methanoindane-2,5-diyl, where all these groups may be     unsubstituted or mono- or polysubstituted by L, -   L denotes P, P-Sp-, OH, CH₂OH, F, Cl, Br, I, —CN, —NO₂, —NCO, —NCS,     —OCN, —SCN, —C(═O)N(R^(x))₂, —C(═O)Y¹, —C(═O)R^(x), —N(R^(x))₂,     optionally substituted silyl, optionally substituted aryl having 6     to 20 C atoms, or straight-chain or branched alkyl, alkoxy,     alkylcarbonyl, alkoxycarbonyl, alkylcarbonyloxy or alkoxycarbonyloxy     having 1 to 25 C atoms, in which, in addition, one or more H atoms     may be replaced by F, Cl, P or P-Sp-, -   P denotes a polymerisable group, -   Y¹ denotes halogen, -   R^(x) denotes P, P-Sp-, H, halogen, straight-chain, branched or     cyclic alkyl having 1 to 25 C atoms, in which, in addition, one or     more non-adjacent CH₂ groups may be replaced by —O—, —S—, —CO—,     —CO—O—, —O—CO—, —O—CO—O— in such a way that O and/or S atoms are not     linked directly to one another, and in which, in addition, one or     more H atoms may be replaced by F, Cl, P or P-Sp-, an optionally     substituted aryl or aryloxy group having 6 to 40 C atoms, or an     optionally substituted heteroaryl or heteroaryloxy group having 2 to     40 C atoms.

Very particular preference is given to compounds of the formula M in which one of R^(Ma) and R^(Mb) or both denote(s) P or P-Sp-.

Suitable and preferred mesogenic comonomers, particularly for use in PS VA displays, are selected, for example, from the following formulae:

in which the individual radicals have the following meanings:

-   P¹, P² and P³ each, independently of one another, denote a     polymerisable group, preferably having one of the meanings indicated     above and below for P, particularly preferably an acrylate,     methacrylate, fluoroacrylate, oxetane, vinyl, vinyloxy or epoxide     group, -   Sp¹, Sp² and Sp³ each, independently of one another, denote a single     bond or a spacer group, preferably having one of the meanings     indicated above and below for Sp, and particularly preferably denote     —(CH₂)_(p1)—, —(CH₂)_(p1)—O—, —(CH₂)_(p1)—CO—O— or     —(CH₂)_(p1)—O—CO—O—, in which p1 is an integer from 1 to 12, and     where the linking to the adjacent ring in the last-mentioned groups     takes place via the O atom,     -   where, in addition, one or more of the radicals P¹-Sp¹-, P²-Sp²-         and P³—Sp³- may denote R^(aa), with the proviso that at least         one of the radicals P¹-Sp¹-, P²—Sp²- and P³—Sp³- present does         not denote R^(aa), -   R^(aa) denotes H, F, Cl, CN or straight-chain or branched alkyl     having 1 to 25 C atoms, in which, in addition, one or more     non-adjacent CH₂ groups may each be replaced, independently of one     another, by C(R⁰)═C(R⁰⁰)—, —C≡C—, —N(R⁰)—, —O—, —S—, —CO—, —CO—O—,     —O—CO—, —O—CO—O— in such a way that O and/or S atoms are not linked     directly to one another, and in which, in addition, one or more H     atoms may be replaced by F, Cl, CN or P¹-Sp¹-, particularly     preferably straight-chain or branched, optionally mono- or     polyfluorinated alkyl, alkoxy, alkenyl, alkynyl, alkylcarbonyl,     alkoxycarbonyl, alkylcarbonyloxy or alkoxycarbonyloxy having 1 to 12     C atoms (where the alkenyl and alkynyl radicals have at least two C     atoms and the branched radicals have at least three C atoms), -   R⁰, R⁰⁰ each, independently of one another and identically or     differently on each occurrence, denote H or alkyl having 1 to 12 C     atoms, -   R^(y) and R^(z) each, independently of one another, denote H, F, CH₃     or CF₃, -   X¹, X² and X³ each, independently of one another, denote —CO—O—,     —O—CO—or a single bond, -   Z¹ denotes —O—, —CO—, —C(R^(y)R^(z))— or —CF₂CF₂—, -   Z² and Z³ each, independently of one another, denote —CO—O—, —O—CO—,     —CH₂O—, —OCH₂—, —CF₂O—, —OCF₂— or —(CH₂)_(n)—, where n is 2, 3 or 4, -   L on each occurrence, identically or differently, denotes F, Cl, CN     or straight-chain or branched, optionally mono- or polyfluorinated     alkyl, alkoxy, alkenyl, alkynyl, alkylcarbonyl, alkoxycarbonyl,     alkylcarbonyloxy or alkoxycarbonyloxy having 1 to 12 C atoms,     preferably F, -   L′ and L″ each, independently of one another, denote H, F or Cl, -   r denotes 0, 1, 2, 3 or 4, -   s denotes 0, 1, 2 or 3, -   t denotes 0, 1 or 2, -   x denotes 0 or 1.

In the compounds of formulae M1 to M41

is preferably

wherein L on each occurrence, identically or differently, has one of the meanings given above or below, and is preferably F, Cl, CN, NO₂, CH₃, C₂H₅, C(CH₃)₃, CH(CH₃)₂, CH₂CH(CH₃)C₂H₅, OCH₃, OC₂H₅, COCH₃, COC₂H₅, COOCH₃, COOC₂H₅, CF₃, OCF₃, OCHF₂, OC₂F₅ or P-Sp-, very preferably F, Cl, CN, CH₃, C₂H₅, OCH₃, COCH₃, OCF₃ or P-Sp-, more preferably F, Cl, CH₃, OCH₃, COCH₃ or OCF₃, especially F or CH₃.

Suitable polymerisable compounds are furthermore listed, for example, in Table D. LC mixtures containing at least one polymerisable compound listed in Table D are especially preferred.

The liquid-crystalline media in accordance with the present application preferably comprise in total 0.1 to 10%, preferably 0.2 to 4.0%, particularly preferably 0.2 to 2.0%, of polymerisable compounds.

Particular preference is given to the polymerisable compounds of the formula M.

The polymerisable compounds are preferably polymerised by photopolymerisation, for example by UV irradiation, often in the presence of at least one suitable initiator. The polymerisation takes place under conditions where the single components of the liquid crystalline mixture as such containing for example single compounds containing an alkenyl side chain like CC-n-V or an alkenyloxy side chain do not polymerize. Suitable conditions for the polymerisation and suitable types and amounts of initiator(s) are known to a person skilled in the art and are described in the literature. Suitable for free-radical polymerisation are, for example, commercially available photoinitiators, for example Irgacure® 651, Irgacure® 184 or Darocure® 1173 (BASF). The polymerisable compound(s) preferably comprise from 0 to 5% by weight, particularly preferably 0.1 to 3% by weight of one or more photoinitiators.

The combination of at least two liquid crystalline compounds, at least one self-aligning additive and preferably with at least one polymerisable compound, in particular one selected from the formula M and/or the formulae M1 to M41, produces low threshold voltages, low rotational viscosities, very good low temperature stabilities (LTS) in the media but at the same time high clearing points and high HR values, and enables the setting or a pretilt angle in VA displays without the need of any alignment layer, e.g., a polyimide layer.

The mixtures according to the invention may furthermore comprise conventional additives, such as, for example, stabilisers, antioxidants, UV absorbers, nanoparticles, microparticles, etc.

The structure of the liquid-crystal displays according to the invention corresponds to the usual geometry, as described, for example, in EP 0 240 379.

Throughout the patent application, 1,4-cyclohexylene rings and 1,4-phenylene rings are depicted as follows:

Throughout the patent application and in the working examples, the structures of the liquid-crystalline compounds are indicated by means of acronyms. Unless indicated otherwise, the transformation into chemical formulae is carried out in accordance with Tables 1-3. All radicals C_(n)H_(2n+1), C_(m)H_(2m+1) and C_(m′)H_(2m′+1) or C_(n)H_(2n) and C_(m)H_(2m) are straight-chain alkyl radicals or alkylene radicals in each case having n, m, m′ or z C atoms respectively. n, m, m′, z each denote, independently of one another, 1, 2, 3, 4, 5, 6, 7, 8, 9, 10, 11 or 12, preferably 1, 2, 3, 4, 5 or 6. In Table 1 the ring elements of the respective compound are coded, in Table 2 the bridging members are listed and in Table 3 the meanings of the symbols for the left-hand or right-hand side chains of the compounds are indicated.

TABLE 1 Ring elements

  A

  AI

  B

  B(S)

  C

  D

  DI

  F

  FI

  G

  GI

  K

  L

  LI

  M

  MI

  N

  NI

  P

  S

  U

  UI

  Y

  Y(F,Cl)

  Y(Cl,F)

TABLE 2 Bridging members E —CH₂CH₂— V —CH═CH— T —C≡C— W —CF₂CF₂— Z —COO— ZI —OCO— O —CH₂O— OI —OCH₂— Q —CF₂O— QI —OCF₂—

TABLE 3 Side chains Left-hand side chain Right-hand side chain n- C_(n)H_(2n+1)— -n —C_(n)H_(2n+1) nO- C_(n)H_(2n+1)—O— -On —O—C_(n)H_(2n+1) V- CH₂═CH— -V —CH═CH₂ nV- C_(n)H_(2n+1)—CH═CH— -nV —C_(n)H_(2n)—CH═CH₂ Vn- CH₂═CH—C_(n)H_(2n)— -Vn —CH═CH—C_(n)H_(2n+1) nVm- C_(n)H_(2n+1)—CH═CH—C_(m)H_(2m)— -nVm —C_(n)H_(2n)—CH═CH—C_(m)H_(2m+1) N- N≡C— -N —C≡N F- F— -F —F Cl- Cl— -Cl —Cl M- CFH₂— -M —CFH₂ D- CF₂H— -D —CF₂H T- CF₃— -T —CF₃ MO- CFH₂O— -OM —OCFH₂ DO- CF₂HO— -OD —OCF₂H TO- CF₃O— -OT —OCF₃ T- CF₃— -T —CF₃ A- H—C≡C— -A —C≡C—H

Besides the compounds of the formulae IIA and/or IIB and/or IIC, one or more compounds of the formula I and at least one compound of the formulae I-A to I-K the mixtures according to the invention preferably comprise one or more of the compounds from Table A indicated below.

TABLE A

  AlK-n-F

  AlY-n-Om

  AY-n-Om

  B-nO-Om

  B-n-Om

  B(S)-nO-Om

  B(S)-n-Om

  CB(S)-n-(O)m

  CB-n-m

  CB-n-Om

  PB-n-m

  PB-n-Om

  BCH-nm

  BCH-nmF

  BCN-nm

  C-1V-V1

  CY-n-Om

  CY(F,Cl)-n-Om

  CY(Cl,F)-n-Om

  CCY-n-Om

  CCY(F,Cl)-n-Om

  CCY(Cl,F)-n-Om

  CCY-n-m

  CCY-V-m

  CCY-Vn-m

  CCY-n-OmV

  CBC-nmF

  CBC-nm

  CCP-V-m

  CCP-Vn-m

  CCP-nV-m

  CCP-n-m

  CPYP-n-(O)m

  CYYC-n-m

  CCYY-n-(O)m

  CCY-n-O2V

  CCH-nOm

  CY-n-m

  CCH-nm

  CC-n-V

  CC-n-V1

  CC-n-Vm

  CC-2V-V2

  CVC-n-m

  CC-n-mV

  CCOC-n-m

  CP-nOmFF

  CH-nm

  CEY-V-n

  CEY-n-m

  CEY-n-Om

  CVY-V-n

  CY-V-On

  CY-n-O1V

  CY-n-OC(CH₃)═CH₂

  CCN-nm

  CY-n-OV

  CCPC-nm

  CCY-n-zOm

  CPY-n-(O)m

  CPY-V-Om

  CQY-n-(O)m

  CQIY-n-(O)m

  CCQY-n-(O)m

  CCQIY-n-(O)m

  CPQY-n-(O)m

  CPQIY-n-(O)m

  CPYG-n-(O)m

  CCY-V-Om

  CCY-V2-(O)m

  CCY-1V2-(O)m

  CCY-3V-(O)m

  CCVC-n-V

  CPYG-n-(O)m

  CPGP-n-m

  CY-nV-(O)m

  CENaph-n-Om

  COChrom-n-Om

  COChrom-n-m

  CCOChrom-n-Om

  CCOChrom-n-m

  CONaph-n-Om

  CCONaph-n-Om

  CCNaph-n-Om

  CNaph-n-Om

  CETNaph-n-Om

  CTNaph-n-Om

  CK-n-F

  CLY-n-Om

  CLY-n-m

  LYLI-n-m

  CYLI-n-m

  LY-n-(O)m

  COYOICC-n-m

  COYOIC-n-V

  CCOY-V-O2V

  COY-n-Om

  COY-n-m

  CCOY-V-O3V

  CCOY-V-Om

  CCOY-1V-Om

  CCOY-n-Om

  D-nOmFF

  PCH-nm

  PCH-nOm

  PGIGI-n-F

  PGP-n-m

  PPGU-n-F

  PYP-n-mV

  PYP-n-m

  PYP-n-Om

  PPYY-n-m

  YPY-n-m

  YPY-n-mV

  PY-n-(O)m

  PP-n-Om

  PP-n-m

  CB-n-(O)m

  B-nO-(O)m

  DFDBC-n(O)-(O)m

  Y-nO-Om

  Y-nO-OmV

  Y-nO-OmVm'

  CC-n-O

  CC-n-1O

  PPGU-n-F

  Y-nO-OmVm'

  YPY-n-mV

  PY-n-m

  PY-n-Om

  PTP-nOmFF

  CPTP-nOmFF

  PPTUI-n-m

  CPTP-nOm

  CPTP-nm

  PTP-nOm

  PTP-nm

  C-DFDBC-n-(O)m

  DFDBC-n(O)-(O)m

  Y-nO-Om

  Y-nO-OmV

  Y-nO-OmVm' The following abbreviations are used: (n, m, m', z: each, independently of one another, 1, 2, 3, 4, 5 or 6; (O)C_(m)H_(2m+1) denotes OC_(m)H_(2m+1) or C_(m)H_(2m+1))

The liquid-crystal mixtures which can be used in accordance with the invention are prepared in a manner which is conventional per se. In general, the desired amount of the components used in lesser amount is dissolved in the components making up the principal constituent, advantageously at elevated temperature. It is also possible to mix solutions of the components in an organic solvent, for example in acetone, chloroform or methanol, and to remove the solvent again, for example by distillation, after thorough mixing.

By means of suitable additives, the liquid-crystal phases according to the invention can be modified in such a way that they can be employed in any type of, for example, ECB, VAN, GH or ASM-VA, IPS, FFS, PS-VA, PS-IPS, PS-FFS LCD display that has been disclosed to date.

The dielectrics may also comprise further additives known to the person skilled in the art and described in the literature, such as, for example, UV absorbers, antioxidants, nanoparticles and free-radical scavengers. For example, 0-15% of pleochroic dyes, stabilisers or chiral dopants may be added. Suitable stabilisers for the mixtures according to the invention are, in particular, those listed in Table C.

For example, 0-15% of pleochroic dyes may be added, furthermore conductive salts, preferably ethyldimethyldodecylammonium 4-hexoxybenzoate, tetrabutylammonium tetraphenylboranate or complex salts of crown ethers (cf., for example, Haller et al., Mol. Cryst. Liq. Cryst. Volume 24, pages 249-258 (1973)), may be added in order to improve the conductivity or substances may be added in order to modify the dielectric anisotropy, the viscosity and/or the alignment of the nematic phases. Substances of this type are described, for example, in DE-A 22 09 127, 22 40 864, 23 21 632, 23 38 281, 24 50 088, 26 37 430 and 28 53 728.

Table B shows possible dopants which can be added to the mixtures according to the invention. If the mixtures comprise a dopant, it is employed in amounts of 0.01-4% by weight, preferably 0.1-1.0% by weight.

TABLE B

Stabilisers which can be added, for example, to the mixtures according to the invention in amounts of up to 10% by weight, based on the total amount of the mixture, preferably 0.01 to 6% by weight, in particular 0.1 to 3% by weight, are shown below in Table C. Preferred stabilisers are, in particular, BHT derivatives, for example 2,6-di-tert-butyl-4-alkylphenols, and Tinuvin 770, as well as Tunivin P and Tempol.

TABLE C

(n = 1-12)

Preferred reactive mesogens (polymerisable compounds) for use in the mixtures according to the invention, preferably in PSA and PS-VA applications are shown in Table D below:

TABLE D

RM-1

RM-2

RM-3

RM-4

RM-5

RM-6

RM-7

RM-8

RM-9

RM-10

RM-11

RM-12

RM-13

RM-14

RM-15

RM-16

RM-17

RM-18

RM-19

RM-20

RM-21

RM-22

RM-23

RM-24

RM-25

RM-26

RM-27

RM-28

RM-29

RM-30

RM-31

RM-32

RM-33

RM-34

RM-35

RM-36

RM-37

RM-38

RM-39

RM-40

RM-41

RM-42

RM-43

RM-44

RM-45

RM-46

RM-47

RM-48

RM-49

RM-50

RM-51

RM-52

RM-53

RM-54

RM-55

RM-56

RM-57

RM-58

RM-59

RM-60

RM-61

RM-62

RM-63

RM-64

RM-65

RM-66

RM-67

RM-68

RM-69

RM-70

RM-71

RM-72

RM-73

RM-74

RM-75

RM-76

RM-77

RM-78

RM-79

RM-80

RM-81

RM-82

RM-83

RM-84

RM-85

RM-86

RM-87

RM-88

RM-89

RM-90

RM-91

RM-92

RM-93

RM-94

RM-95

RM-96

RM-97

RM-98

Without further elaboration, it is believed that one skilled in the art can, using the preceding description, utilize the present invention to its fullest extent. The preceding preferred specific embodiments are, therefore, to be construed as merely illustrative, and not limitative of the remainder of the disclosure in any way whatsoever.

In the foregoing and in the examples, all temperatures are set forth uncorrected in degrees Celsius and, all parts and percentages are by weight, unless otherwise indicated.

The entire disclosures of all applications, patents and publications, cited herein and of corresponding application No EP 14002851.5, filed Aug. 15, 2014 are incorporated by reference herein.

EXAMPLES

The following examples are intended to explain the invention without restricting it. In the examples, m.p. denotes the melting point and C denotes the clearing point of a liquid-crystalline substance in degrees Celsius; boiling points are denoted by b.p. Furthermore:

C denotes crystalline solid state, S denotes smectic phase (the index denotes the phase type), N denotes nematic state, Ch denotes cholesteric phase, I denotes isotropic phase, T_(g) denotes glass transition temperature.

The number between two symbols indicates the conversion temperature in degrees Celsius.

Conventional work-up means: water is added, the mixture is extracted with methylene chloride, the phases are separated, the organic phase is dried and evaporated, and the product is purified by crystallisation and/or chromatography.

Example 1 Step 1.1

4-Propyl-4′-bromo-2-fluorobiphenyl is prepared according to WO89/03821.

Step 1.2: 2′-Fluoro-4′-propyl-biphenyl-4-carboxylic acid

29.3 g (0.100 mol) 4-propyl-4′-bromo-2-fluorobiphenyl are dissolved in THF (800 ml) and cooled to −70° C. After addition of 66 ml (0.105 mol) n-butyl lithium the reaction is stirred for 30 min and then a CO₂ stream is passed through the solution until the exothermic reaction ceases. The reaction is warmed to −10° C., poured onto water and acidified with conc. hydrochloric acid. The mixture is extracted with methyl tert. butyl ether (MBT ether) and dried over sodium sulfate. The solvent is evaporated and the residue is recrystallised from n-heptane to give 2′-fluoro-4′-propyl-biphenyl-4-carboxylic acid as colourless crystals.

Step 1.3: (2′-Fluoro-4′-propyl-biphenyl-4-yl)-methanol

1.45 g (38 mmol) lithiumaluminium hydride are placed in a flask under toluene (10 ml) and a solution of 12.0 g (46.0 mmol) 2′-fluoro-4′-propylbiphenyl-4-carboxylic acid in THF (250 ml) is added dropwise. The reaction is stirred at room temperature over night and is then hydrolised carefully with 2M hydrochloric acid (100 ml) under ice-cooling. After addition of MTB-ether (50 ml) the aqueous layer was separated and extracted tree times with MTB-ether. The combined organic layers are washed saturated sodium bicarbonate solution and dried over sodium sulfate. The solvent is evaporated and the crude product filtered through silica with heptane/ethyl acetate (8:2). Crystallisation from n-heptane gives (2′-fluoro-4′-propyl-biphenyl-4-yl)-methanol as colourless crystals.

K 50 l

Above and below,

-   V₀ denotes the threshold voltage, capacitive [V] at 20° C. -   Δn denotes the optical anisotropy measured at 20° C. and 589 nm -   Δ∈ denotes the dielectric anisotropy at 20° C. and 1 kHz -   cl.p. denotes the clearing point [° C.] -   K₁ denotes the elastic constant, “splay” deformation at 20° C. [pN] -   K₃ denotes the elastic constant, “bend” deformation at 20° C. [pN] -   γ₁ denotes the rotational viscosity measured at 20° C. [mPa·s],     determined by the rotation method in a magnetic field -   LTS denotes the low-temperature stability (nematic phase),     determined in test cells

The display used for measurement of the threshold voltage has two plane-parallel outer plates at a separation of 20 μm and electrode layers with overlying alignment layers of JALS-2096 on the insides of the outer plates, which effect a homeotropic alignment of the liquid crystals.

All concentrations in this application relate to the corresponding mixture or mixture component, unless explicitly indicated otherwise. All physical properties are determined as described in “Merck Liquid Crystals, Physical Properties of Liquid Crystals”, status November 1997, Merck KGaA, Germany, and apply for a temperature of 20° C., unless explicitly indicated otherwise.

Unless indicated otherwise, parts or percent data denote parts by weight or percent by weight.

Mixture Examples

For the production of the so-called SA (self-alignment)-VA mixtures according to the present invention the following host mixtures H1 to H120 are used:

H1: Nematic Host-Mixture

CY-3-O2 10.00% Clearing point [° C.]: 100 CY-3-O4 20.00% Δn [589 nm, 20° C.]: 0.0865 CY-5-O4 20.00% Δε [1 kHz, 20° C.]: −5.4 CCY-3-O2 6.00% ε_(||) [1 kHz, 20° C.]: 3.9 CCY-3-O3 6.00% ε_(⊥) [1 kHz, 20° C.]: 9.3 CCY-4-O2 6.00% K₁ [pN, 20° C.]: 15.6 CCY-5-O2 6.00% K₃ [pN, 20° C.]: 16.6 CH-33 3.00% V₀ [20° C., V]: 1.84 CH-35 3.50% CH-43 3.50% CH-45 3.50% CCPC-33 4.00% CCPC-34 4.50% CCPC-35 4.00% H2: Nematic Host-Mixture

Y-4O-O4 12.00% Clearing point [° C.]: 89 CCY-3-O2 5.00% Δn [589 nm, 20° C.]: 0.2108 CCY-3-O3 4.00% Δε [1 kHz, 20° C.]: −3.2 CC-4-V 10.00% ε_(||) [1 kHz, 20° C.]: 4.3 CCP-V2-1 12.00% ε_(⊥) [1 kHz, 20° C.]: 7.5 PPTUI-3-2 15.00% K₃ [pN, 20° C.]: 19.3 PPTUI-3-4 8.00% K₃/K₁ [20 ° C.]: 1.19 PTP-3O2FF 12.00% V₀ [20° C., V]: 2.58 PTP-5O2FF 12.00% CPTP-3O2FF 5.00% CPTP-5O2FF 5.00% H3: Nematic Host-Mixture

Y-4O-O4 10.00% Clearing point [° C.]: 91 CCY-3-O2 6.00% Δn [589 nm, 20° C.]: 0.2099 CCY-3-O3 3.50% Δε [1 kHz, 20° C.]: −3.0 CC-4-V 13.50% ε_(||) [1 kHz, 20° C.]: 4.2 CCP-V2-1 10.00% ε_(⊥) [1 kHz, 20° C.]: 7.2 PPTUI-3-2 15.00% K₃ [pN, 20° C.]: 19.2 PPTUI-3-4 8.00% K₃/K₁ [20 ° C.]: 1.21 PTP-3O2FF 12.00% γ₁ [mPa · s, 20° C.]: 190 PTP-5O2FF 12.00% V₀ [20° C., V]: 2.66 CPTP-3O2FF 5.00% CPTP-5O2FF 5.00% H4: Nematic Host-Mixture

Y-4O-O4 12.00% Clearing point [° C.]: 89 CCY-3-O2 4.00% Δn [589 nm, 20° C.]: 0.2089 CC-4-V 13.50% Δε [1 kHz, 20° C.]: −2.8 CC-5-V 4.00% ε_(||) [1 kHz, 20° C.]: 4.3 PPTUI-3-2 15.00% ε_(⊥) [1 kHz, 20° C.]: 7.1 PPTUI-3-4 9.50% K₃ [pN, 20° C.]: 19.0 PTP-3O2FF 12.00% K₃/K₁ [20° C.]: 1.27 PTP-5O2FF 12.00% V₀ [20° C., V]: 2.70 CPTP-3O2FF 5.00% CPTP-5O2FF 5.00% CCPC-33 4.00% CCPC-34 4.00% H5: Nematic Host-Mixture

Y-4O-O4 12.00% Clearing point [° C.]: 91 CCY-3-O2 2.50% Δn [589 nm, 20° C.]: 0.2101 CPY-2-O2 3.50% Δε [1 kHz, 20° C.]: −3.0 CC-4-V 13.50% ε_(||) [1 kHz, 20° C.]: 4.3 CC-5-V 2.50% Δε_(⊥) [1 kHz, 20° C.]: 7.3 PPTUI-3-2 15.00% K₃ [pN, 20° C.]: 19.3 PPTUI-3-4 8.50% K₃/K₁ [20° C.]: 1.32 PTP-3O2FF 12.00% γ₁ [mPa · s, 20° C.]: 201 PTP-5O2FF 12.00% V₀ [20° C., V]: 2.64 CPTP-3O2FF 5.00% CPTP-5O2FF 5.00% CCPC-33 4.50% CCPC-34 4.00% H6: Nematic Host-Mixture

Y-4O-O4 10.00% Clearing point [° C.]: 91 CCY-3-O2 5.50% Δn [589 nm, 20° C.]: 0.2102 CPY-2-O2 3.50% Δε [1 kHz, 20° C.]: −3.0 CC-4-V 13.50% ε_(||) [1 kHz, 20° C.]: 4.2 CC-5-V 5.00% ε_(⊥) [1 kHz, 20° C.]: 7.2 PPTUI-3-2 15.00% K₃ [pN, 20° C.]: 19.2 PPTUI-3-4 8.50% K₃/K₁ [20° C.]: 1.25 PTP-3O2FF 12.00% γ₁ [mPa · s, 20° C.]: 195 PTP-5O2FF 12.00% V₀ [20° C., V]: 2.66 CPTP-3O2FF 5.00% CPTP-5O2FF 5.00% CCPC-33 5.00% H7: Nematic Host-Mixture

Y-4O-O4 15.00% Clearing point [° C.]: 88 CC-4-V 13.50% Δn [589 nm, 20° C.]: 0.2089 PPTUI-3-2 15.00% Δε [1 kHz, 20° C.]: −3.0 PPTUI-3-4 9.50% ε_(||) [1 kHz, 20° C.]: 4.4 PTP-3O2FF 12.00% ε_(⊥) [1 kHz, 20° C.]: 7.4 PTP-5O2FF 12.00% K₃ [pN, 20° C.]: 19.1 CPTP-3O2FF 5.00% K₃/K₁ [20° C.]: 1.30 CPTP-5O2FF 5.00% V₀ [20° C., V]: 2.67 CCPC-33 4.50% CCPC-34 4.50% CCPC-35 4.00% stabilised with 0.02% of

H8: Nematic Host-Mixture

Y-4O-O4 15.00% Clearing point [° C.]: 90 CPY-2-O2 1.50% Δn [589 nm, 20° C.]: 0.2115 CC-4-V 12.00% Δε [1 kHz, 20° C.]: −3.1 PPTUI-3-2 15.00% ε_(∥) [1 kHz, 20° C.]: 4.5 PPTUI-3-4 9.00% ε_(⊥) [1 kHz, 20° C.]: 7.6 PTP-3O2FF 12.00% K₃ [pN, 20° C.]: 19.6 PTP-5O2FF 12.00% K₃/K₁ [20° C.]: 1.30 CPTP-3O2FF 5.00% V₀ [20° C., V]: 2.63 CPTP-5O2FF 5.00% CCPC-33 4.50% CCPC-34 4.50% CCPC-35 4.50%

H9: Nematic Host-Mixture

CY-3-O4 5.50% Clearing point [° C.]: 91 PY3-O2 8.00% Δn [589 nm, 20° C.]: 0.2099 CCY-3-O2 5.50% Δε [1 kHz, 20° C.]: −3.0 CCY-3-O3 5.00% ε_(∥) [1 kHz, 20° C.]: 3.9 CC-4-V 13.00% ε_(⊥) [1 kHz, 20° C.]: 6.9 CC-5-V 8.00% K₃ [pN, 20° C.]: 19.6 PPTUI-3-2 15.00% K₃/K₁ [20° C.]: 1.20 PPTUI-3-4 6.00% γ₁ [mPa · s, 20° C.]: 195 PTP-3O2FF 12.00% V₀ [20° C., V]: 2.68 PTP-5O2FF 12.00% CPTP-3O2FF 5.00% CPTP-5O2FF 5.00% H10: Nematic Host-Mixture

Y-4O-O4 15.50% Clearing point [° C.]: 90 CC-4-V 12.00% Δn [589 nm, 20° C.]: 0.2098 PPTUI-3-2 15.00% Δε [1 kHz, 20° C.]: −3.1 PPTUI-3-4 8.50% ε_(∥) [1 kHz, 20° C.]: 4.5 PTP-3O2FF 12.00% ε_(⊥) [1 kHz, 20° C.]: 7.6 PTP-5O2FF 12.00% K₃ [pN, 20° C.]: 19.5 CPTP-3O2FF 5.00% K₃/K₁ [20° C.]: 1.28 CPTP-5O2FF 5.00% γ₁ [mPa · s, 20° C.]: 227 CCPC-33 5.00% V₀ [20° C., V]: 2.65 CCPC-34 5.00% CCPC-35 5.00% H11: Nematic Host-Mixture

Y-4O-O4 13.50% Clearing point [° C.]: 80 CC-4-V 14.00% Δn [589 nm, 20° C.]: 0.2076 CCP-V-1 9.00% Δε [1 kHz, 20° C.]: −2.6 BCH-32 5.00% ε_(∥) [1 kHz, 20° C.]: 4.3 CPTP-31 5.00% ε_(⊥) [1 kHz, 20° C.]: 6.9 PPTUI-3-2 19.50% K₃ [pN, 20° C.]: 16.9 PTP-3O2FF 12.00% K₃/K₁ [20° C.]: 1.23 PTP-5O2FF 12.00% γ₁ [mPa · s, 20° C.]: 145 CPTP-3O2FF 5.00% V₀ [20° C., V]: 2.67 CPTP-5O2FF 5.00% H12: Nematic Host-Mixture

Y-4O-O4 13.00% Clearing point [° C.]: 90 CPY-3-O2 4.00% Δn [589 nm, 20° C.]: 0.2097 CC-4-V 5.00% Δε [1 kHz, 20° C.]: −3.0 CCP-V-1 12.00% ε_(∥) [1 kHz, 20° C.]: 4.3 CCP-V2-1 12.00% ε_(⊥) [1 kHz, 20° C.]: 7.3 PPTUI-3-2 15.00% PPTUI-3-4 5.00% PTP-3O2FF 12.00% PTP-5O2FF 12.00% CPTP-3O2FF 5.00% CPTP-5O2FF 5.00% H13: Nematic Host-Mixture

Y-4O-O4 12.50% Clearing point [° C.]: 91 CPY-3-O2 4.50% Δn [589 nm, 20° C.]: 0.2097 CC-4-V 6.00% Δε [1 kHz, 20° C.]: −3.0 CCP-V-1 11.00% ε_(∥) [1 kHz, 20° C.]: 4.3 CCP-V2-1 12.00% ε_(⊥) [1 kHz, 20° C.]: 7.3 PPTUI-3-2 15.00% K₃ [pN, 20° C.]: 19.8 PPTUI-3-4 5.00% K₃/K₁ [20° C.]: 1.22 PTP-3O2FF 12.00% γ₁ [mPa · s, 20° C.]: 186 PTP-5O2FF 12.00% V₀ [20° C., V]: 2.69 CPTP-3O2FF 5.00% CPTP-5O2FF 5.00% H14: Nematic Host-Mixture

Y-4O-O4 10.50% Clearing point [° C.]: 91 CPY-2-O2 4.00% Δn [589 nm, 20° C.]: 0.2102 CPY-3-O2 4.00% Δε [1 kHz, 20° C.]: −3.0 CC-4-V 10.50% ε_(∥) [1 kHz, 20° C.]: 4.2 CCP-V-1 6.00% ε_(⊥) [1 kHz, 20° C.]: 7.2 CCP-V2-1 11.00% K₃ [pN, 20° C.]: 19.3 PPTUI-3-2 15.00% K₃/K₁ [20° C.]: 1.22 PPTUI-3-4 5.00% γ₁ [mPa · s, 20° C.]: 187 PTP-3O2FF 12.00% V₀ [20° C., V]: 2.67 PTP-5O2FF 12.00% CPTP-3O2FF 5.00% CPTP-5O2FF 5.00% H15: Nematic Host-Mixture

Y-4O-O4 10.00% Clearing point [° C.]: 91 CCY-3-O2 4.50% Δn [589 nm, 20° C.]: 0.2106 CPY-3-O2 4.50% Δε [1 kHz, 20° C.]: −3.0 CC-4-V 14.00% ε_(||) [1 kHz, 20° C.]: 4.2 CCP-V2-1 11.00% ε_(⊥) [1 kHz, 20° C.]: 7.2 PPTUI-3-2 15.00% K₃ [pN, 20° C.]: 19.3 PPTUI-3-4 7.00% K₃/K₁ [20° C.]: 1.19 PTP-3O2FF 12.00% γ₁ [mPa · s, 20° C.]: 186 PTP-5O2FF 12.00% V₀ [20° C., V]: 2.68 CPTP-3O2FF 5.00% CPTP-5O2FF 5.00% H16: Nematic Host-Mixture

Y-4O-O4 12.50% Clearing point [° C.]: 91 CPY-3-O2 4.50% Δn [589 nm, 20° C.]: 0.2106 CC-4-V 5.50% Δε [1 kHz, 20° C.]: −3.0 CCP-V-1 12.00% ε_(||) [1 kHz, 20° C.]: 4.3 CCP-V2-1 8.00% ε_(⊥) [1 kHz, 20° C.]: 7.3 BCH-32 5.00% K₃ [pN, 20° C.]: 19.5 PPTUI-3-2 15.00% K₃/K₁ [20° C.]: 1.22 PPTUI-3-4 3.50% γ₁ [mPa · s, 20° C.]: 190 PTP-3O2FF 12.00% V₀ [20° C., V]: 2.69 PTP-5O2FF 12.00% CPTP-3O2FF 5.00% CPTP-5O2FF 5.00% H17: Nematic Host-Mixture

Y-4O-O4 12.50% Clearing point [° C.]: 91 CPY-3-O2 5.00% Δn [589 nm, 20° C.]: 0.2090 CC-4-V 6.00% Δε [1 kHz, 20° C.]: −3.0 CCP-V-1 12.00% ε_(||) [1 kHz, 20° C.]: 4.3 CCP-V2-1 7.50% ε_(⊥) [1 kHz, 20° C.]: 7.3 BCH-32 5.00% K₃ [pN, 20° C.]: 19.4 PPTUI-3-2 18.00% K₃/K₁ [20° C.]: 1.22 PTP-3O2FF 12.00% γ₁ [mPa · s, 20° C.]: 181 PTP-5O2FF 12.00% V₀ [20° C., V]: 2.66 CPTP-3O2FF 5.00% CPTP-5O2FF 5.00% H18: Nematic Host-Mixture

Y-4O-O4 12.50% Clearing point [° C.]: 90 CPY-3-O2 4.50% Δn [589 nm, 20° C.]: 0.2091 CC-4-V 9.50% Δε [1 kHz, 20° C.]: −3.0 CCP-V-1 5.00% ε_(||) [1 kHz, 20° C.]: 4.2 CCP-V2-1 12.00% ε_(⊥) [1 kHz, 20° C.]: 7.2 CPTP-3-1 6.00% K₃ [pN, 20° C.]: 19.6 PPTUI-3-2 16.50% K₃/K₁ [20° C.]: 1.23 PTP-3O2FF 12.00% γ₁ [mPa · s, 20° C.]: 182 PTP-5O2FF 12.00% V₀ [20° C., V]: 2.70 CPTP-3O2FF 5.00% CPTP-5O2FF 5.00% H18: Nematic Host-Mixture

Y-4O-O4 12.50% Clearing point [° C.]: 91 CPY-3-O2 5.00% Δn [589 nm, 20° C.]: 0.2091 CC-4-V 6.00% Δε [1 kHz, 20° C.]: −3.1 CCP-V-1 11.00% ε_(||) [1 kHz, 20° C.]: 4.2 CCP-V2-1 12.00% ε_(⊥) [1 kHz, 20° C.]: 7.3 PPTUI-3-2 19.50% K₃ [pN, 20° C.]: 19.5 PTP-3O2FF 12.00% K₃/K₁ [20° C.]: 1.20 PTP-5O2FF 12.00% γ₁ [mPa · s, 20° C.]: 188 CPTP-3O2FF 5.00% V₀ [20° C., V]: 2.66 CPTP-5O2FF 5.00% H20: Nematic Host-Mixture

Y-4O-O4 12.50% Clearing point [° C.]: 91 CPY-3-O2 5.00% Δn [589 nm, 20° C.]: 0.2094 CC-4-V 7.00% Δε [1 kHz, 20° C.]: −3.0 CCP-V-1 5.00% ε_(||) [1 kHz, 20° C.]: 4.3 CCP-V2-1 13.00% ε_(⊥) [1 kHz, 20° C.]: 7.3 BCH-32 5.00% K₃ [pN, 20° C.]: 19.7 PPTUI-3-2 18.50% K₃/K₁ [20° C.]: 1.19 PTP-3O2FF 12.00% γ₁ [mPa · s, 20° C.]: 185 PTP-5O2FF 12.00% V₀ [20° C., V]: 2.67 CPTP-3O2FF 5.00% CPTP-5O2FF 5.00% H21: Nematic Host-Mixture

Y-4O-O4 10.00% Clearing point [° C.]: 91 CCY-3-O2 4.50% Δn [589 nm, 20° C.]: 0.2094 CPY-3-O2 4.50% Δε [1 kHz, 20° C.]: −3.1 CC-4-V 12.50% ε_(||) [1 kHz, 20° C.]: 4.1 CCP-V-1 10.00% ε_(⊥) [1 kHz, 20° C.]: 7.2 BCH-32 5.00% K₃ [pN, 20° C.]: 19.2 PPTUI-3-2 19.50% K₃/K₁ [20° C.]: 1.21 PTP-3O2FF 12.00% γ₁ [mPa · s, 20° C.]: 187 PTP-5O2FF 12.00% V₀ [20° C., V]: 2.66 CPTP-3O2FF 5.00% CPTP-5O2FF 5.00% H22: Nematic Host-Mixture

Y-4O-O4 15.00% Clearing point [° C.]: 73 CCY-3-O2 5.00% CPY-3-O2 3.00% CC-3-V 15.00% CCP-V2-1 3.50% PPTUI-3-2 15.00% PPTUI-3-4 9.50% PTP-3O2FF 12.00% PTP-5O2FF 12.00% CPTP-3O2FF 5.00% CPTP-5O2FF 5.00% H23: Nematic Host-Mixture

Y-4O-O4 12.50% Clearing point [° C.]: 90 CPY-3-O2 4.50% Δn [589 nm, 20° C.]: 0.2100 CC-4-V 10.00% Δε [1 kHz, 20° C.]: −3.0 CCP-V2-1 12.50% ε_(||) [1 kHz, 20° C.]: 4.2 BCH-32 5.00% ε_(⊥) [1 kHz, 20° C.]: 7.2 CPTP-31 6.00% K₃ [pN, 20° C.]: 19.3 PPTUI-3-2 15.50% K₃/K₁ [20° C.]: 1.19 PTP-3O2FF 12.00% γ₁ [mPa · s, 20° C.]: 185 PTP-5O2FF 12.00% V₀ [20° C., V]: 2.69 CPTP-3O2FF 5.00% CPTP-5O2FF 5.00% H24: Nematic Host-Mixture

Y-4O-O4 12.50% Clearing point [° C.]: 91 CPY-3-O2 4.50% Δn [589 nm, 20° C.]: 0.2088 CC-4-V 8.00% Δε [1 kHz, 20° C.]: −3.0 CCP-V-1 12.50% ε_(||) [1 kHz, 20° C.]: 4.2 CCP-V2-1 3.00% ε_(⊥) [1 kHz, 20° C.]: 7.2 BCH-32 5.00% K₃ [pN, 20° C.]: 19.6 CPTP-31 6.00% K₃/K₁ [20° C.]: 1.23 PPTUI-3-2 14.50% γ₁ [mPa · s, 20° C.]: 182 PTP-3O2FF 12.00% V₀ [20° C., V]: 2.70 PTP-5O2FF 12.00% CPTP-3O2FF 5.00% CPTP-5O2FF 5.00% H25: Nematic Host-Mixture

Y-4O-O4 12.50% Clearing point [° C.]: 90 CPY-3-O2 5.00% Δn [589 nm, 20° C.]: 0.2117 CC-4-V 12.50% Δε [1 kHz, 20° C.]: −3.1 CVCP-1V-O1 5.00% ε_(||) [1 kHz, 20° C.]: 4.1 PTP-102 5.00% ε_(⊥) [1 kHz, 20° C.]: 7.2 PTP-201 3.00% K₃ [pN, 20° C.]: 20.9 CPTP-301 5.00% K₃/K₁ [20° C.]: 1.38 CPTP-31 6.00% γ₁ [mPa · s, 20° C.]: 193 CPTP-32 6.00% V₀ [20° C., V]: 2.72 CPTP-41 6.00% PTP-3O2FF 12.00% PTP-5O2FF 12.00% CPTP-3O2FF 5.00% CPTP-5O2FF 5.00% H26: Nematic Host-Mixture

Y-4O-O4 14.50% Clearing point [° C.]: 91 CPY-3-O2 2.00% Δn [589 nm, 20° C.]: 0.2103 CC-4-V 12.50% Δε [1 kHz, 20° C.]: −3.1 CVCP-1V-O1 5.00% ε_(||) [1 kHz, 20° C.]: 4.2 PTP-1O2 4.50% ε_(⊥) [1 kHz, 20° C.]: 7.3 CPTP-3O1 5.00% K₃ [pN, 20° C.]: 21.0 CPTP-3O2 4.50% K₃/K₁ [20° C.]: 1.34 CPTP-31 6.00% γ₁ [mPa · s, 20° C.]: 195 CPTP-32 6.00% V₀ [20° C., V]: 2.72 CPTP-41 6.00% PTP-3O2FF 12.00% PTP-5O2FF 12.00% CPTP-3O2FF 5.00% CPTP-5O2FF 5.00% H27: Nematic Host-Mixture

Y-4O-O4 16.00% Clearing point [° C.]: 90 CC-4-V 12.00% Δn [589 nm, 20° C.]: 0.2084 CVCP-1V-O1 5.00% Δε [1 kHz, 20° C.]: −3.1 PTP-102 2.50% ε_(||) [1 kHz, 20° C.]: 4.2 CPTP-301 5.00% ε_(⊥) [1 kHz, 20° C.]: 7.3 CPTP-302 5.00% K₃ [pN, 20° C.]: 20.5 CPTP-303 2.50% K₃/K₁ [20° C.]: 1.31 CPTP-31 6.00% γ₁ [mPa · s, 20° C.]: 194 CPTP-32 6.00% V₀ [20° C., V]: 2.69 CPTP-41 6.00% PTP-3O2FF 12.00% PTP-5O2FF 12.00% CPTP-3O2FF 5.00% CPTP-5O2FF 5.00% H28: Nematic Host-Mixture

Y-4O-O4 12.50% Clearing point [° C.]: 91 CPY-2-O2 5.00% Δn [589 nm, 20° C.]: 0.2093 CC-4-V 12.00% Δε [1 kHz, 20° C.]: −3.1 CCP-V-1 1.50% ε_(||) [1 kHz, 20° C.]: 4.1 CVCP-1V-O1 5.00% ε_(⊥) [1 kHz, 20° C.]: 7.2 PTP-1O2 5.00% K₃ [pN, 20° C.]: 19.4 PTP-2O1 2.00% K₃/K₁ [20° C.]: 1.22 CPTP-3O1 5.00% V₀ [20° C., V]: 2.64 CPTP-31 6.00% CPTP-32 6.00% CPTP-41 6.00% PTP-3O2FF 12.00% PTP-5O2FF 12.00% CPTP-3O2FF 5.00% CPTP-5O2FF 5.00% H29: Nematic Host-Mixture

Y-4O-O4 12.50% Clearing point [° C.]: 92 CPY-3-O2 5.00% Δn [589 nm, 20° C.]: 0.2092 CC-4-V 12.00% Δε [1 kHz, 20° C.]: −3.1 CCP-V-1 3.50% ε_(||) [1 kHz, 20° C.]: 4.0 BCH-32 5.00% ε_(⊥) [1 kHz, 20° C.]: 7.1 PTP-1O2 5.00% K₃ [pN, 20° C.]: 20.2 CPTP-3O1 5.00% K₃/K₁ [20° C.]: 1.25 CPTP-31 6.00% γ₁ [mPa · s, 20° C.]: 193 CPTP-32 6.00% V₀ [20° C., V]: 2.70 CPTP-41 6.00% PTP-3O2FF 12.00% PTP-5O2FF 12.00% CPTP-3O2FF 5.00% CPTP-5O2FF 5.00% H30: Nematic Host-Mixture

Y-4O-O4 12.50% Clearing point [° C.]: 91 CPY-3-O2 5.00% Δn [589 nm, 20° C.]: 0.2108 CC-4-V 7.50% Δε [1 kHz, 20° C.]: −3.1 CCP-V-1 12.00% ε_(∥) [1 kHz, 20° C.]: 4.2 CVCP-1V-O1 5.00% ε_(⊥) [1 kHz, 20° C.]: 7.3 BCH-32 5.50% K₃ [pN, 20° C.]: 19.7 PPTUI-3-2 18.50% K₃/K₁ [20° C.]: 1.25 PTP-3O2FF 12.00% γ₁ [mPa · s, 20° C.]: 193 PTP-5O2FF 12.00% V₀ [20° C., V]: 2.67 CPTP-3O2FF 5.00% CPTP-5O2FF 5.00% H31: Nematic Host-Mixture

Y-4O-O4 12.50% Clearing point [° C.]: 80 CPY-2-O2 2.50% Δn [589 nm, 20° C.]: 0.2081 CC-3-V 16.00% Δε [1 kHz, 20° C.]: −2.7 CCP-V-1 6.00% ε_(∥) [1 kHz, 20° C.]: 4.3 BCH-32 5.00% ε_(⊥) [1 kHz, 20° C.]: 7.0 CPTP-31 5.00% K₃ [pN, 20° C.]: 17.5 PPTUI-3-2 19.00% K₃/K₁ [20° C.]: 1.23 PTP-3O2FF 12.00% γ₁ [mPa · s, 20° C.]: 143 PTP-5O2FF 12.00% V₀ [20° C., V]: 2.67 CPTP-3O2FF 5.00% CPTP-5O2FF 5.00% H32: Nematic Host-Mixture

Y-4O-O4 12.50% Clearing point [° C.]: 91 CPY-3-O2 4.00% Δn [589 nm, 20° C.]: 0.1973 CC-4-V 15.50% Δε [1 kHz, 20° C.]: −3.0 BCH-32 5.00% ε_(∥) [1 kHz, 20° C.]: 4.0 CVCP-1V-O1 5.00% ε_(⊥) [1 kHz, 20° C.]: 7.0 PTP-1O2 3.00% K₃ [pN, 20° C.]: 19.6 CPTP-3O1 3.00% K₃/K₁ [20° C.]: 1.26 CPTP-31 6.00% γ₁ [mPa · s, 20° C.]: 174 CPTP-32 6.00% V₀ [20° C., V]: 2.69 CPTP-41 6.00% PTP-3O2FF 12.00% PTP-5O2FF 12.00% CPTP-3O2FF 5.00% CPTP-5O2FF 5.00% H33: Nematic Host-Mixture

Y-4O-O4 12.00% Clearing point [° C.]: 79 CPY-2-O2 2.00% Δn [589 nm, 20° C.]: 0.2084 CC-4-V 18.50% Δε [1 kHz, 20° C.]: −2.5 CCP-V-1 2.50% ε_(∥) [1 kHz, 20° C.]: 4.3 BCH-32 5.50% ε_(⊥) [1 kHz, 20° C.]: 6.8 CPTP-31 5.50% K₃ [pN, 20° C.]: 16.6 PPTUI-3-2 20.00% K₃/K₁ [20° C.]: 1.19 PTP-3O2FF 12.00% γ₁ [mPa · s, 20° C.]: 142 PTP-5O2FF 12.00% V₀ [20° C., V]: 2.68 CPTP-3O2FF 5.00% CPTP-5O2FF 5.00% H34: Nematic Host-Mixture

Y-4O-O4 12.50% Clearing point [° C.]: 90 CPY-3-O2 5.00% Δn [589 nm, 20° C.]: 0.1985 CC-4-V 13.50% Δε [1 kHz, 20° C.]: −3.1 CCP-V-1 5.00% ε_(∥) [1 kHz, 20° C.]: 4.1 CVCP-1V-O1 5.00% ε_(⊥) [1 kHz, 20° C.]: 7.2 PTP-102 5.00% K₃ [pN, 20° C.]: 19.9 CPTP-301 2.00% K₃/K₁ [20° C.]: 1.28 CPTP-31 6.00% γ₁ [mPa · s, 20° C.]: 176 CPTP-32 6.00% V₀ [20° C., V]: 2.67 CPTP-41 6.00% PTP-3O2FF 12.00% PTP-5O2FF 12.00% CPTP-3O2FF 5.00% CPTP-5O2FF 5.00% H35: Nematic Host-Mixture

Y-4O-O4 12.50% Clearing point [° C.]: 79 CPY-2-O2 2.50% Δn [589 nm, 20° C.]: 0.2105 CC-3-V 17.00% Δε [1 kHz, 20° C.]: −2.7 CCP-V-1 3.00% ε_(∥) [1 kHz, 20° C.]: 4.2 BCH-32 6.00% ε_(⊥) [1 kHz, 20° C.]: 6.9 CPTP-31 6.00% K₃ [pN, 20° C.]: 17.6 PPTUI-3-2 19.00% K₃/K₁ [20° C.]: 1.23 PTP-3O2FF 12.00% γ₁ [mPa · s, 20° C.]: 143 PTP-5O2FF 12.00% V₀ [20° C., V]: 2.69 CPTP-3O2FF 5.00% CPTP-5O2FF 5.00% H36: Nematic Host-Mixture

Y-4O-O4 14.00% Clearing point [° C.]: 80 CC-3-V 12.00% Δn [589 nm, 20° C.]: 0.2093 CCP-V-1 10.00% Δε [1 kHz, 20° C.]: −2.7 BCH-32 6.00% ε_(∥) [1 kHz, 20° C.]: 4.3 CPTP-31 5.00% ε_(⊥) [1 kHz, 20° C.]: 7.0 PPTUI-3-2 19.00% K₃ [pN, 20° C.]: 17.7 PTP-3O2FF 12.00% K₃/K₁ [20° C.]: 1.22 PTP-5O2FF 12.00% γ₁ [mPa · s, 20° C.]: 147 CPTP-3O2FF 5.00% V₀ [20° C., V]: 2.68 CPTP-5O2FF 5.00% H37: Nematic Host-Mixture

Y-4O-O4 11.00% Clearing point [° C.]: 80 CPY-2-O2 5.50% Δn [589 nm, 20° C.]: 0.2098 CC-3-V 20.00% Δε [1 kHz, 20° C.]: −2.8 BCH-32 5.00% ε_(∥) [1 kHz, 20° C.]: 4.2 CPTP-31 5.00% ε_(⊥) [1 kHz, 20° C.]: 7.0 PPTUI-3-2 19.50% K₃ [pN, 20° C.]: 17.6 PTP-3O2FF 12.00% K₃/K₁ [20° C.]: 1.21 PTP-5O2FF 12.00% γ₁ [mPa · s, 20° C.]: 146 CPTP-3O2FF 5.00% V₀ [20° C., V]: 2.66 CPTP-5O2FF 5.00% H38: Nematic Host-Mixture

Y-4O-O4 12.50% Clearing point [° C.]: 79 CPY-2-O2 2.50% Δn [589 nm, 20° C.]: 0.2096 CC-3-V 16.50% Δε [1 kHz, 20° C.]: −2.7 CCP-V-1 4.50% ε_(∥) [1 kHz, 20° C.]: 4.2 BCH-32 5.00% ε_(⊥) [1 kHz, 20° C.]: 6.9 CPTP-31 6.00% K₃ [pN, 20° C.]: 17.7 PPTUI-3-2 19.00% K₃/K₁ [20° C.]: 1.24 PTP-3O2FF 12.00% γ₁ [mPa · s, 20° C.]: 145 PTP-5O2FF 12.00% V₀ [20° C., V]: 2.68 CPTP-3O2FF 5.00% CPTP-5O2FF 5.00% H39: Nematic Host-Mixture

Y-4O-O4 12.50% Clearing point [° C.]: 80 CPY-2-O2 2.50% Δn [589 nm, 20° C.]: 0.2110 CC-3-V 18.00% Δε [1 kHz, 20° C.]: −2.7 BCH-32 6.00% ε_(∥) [1 kHz, 20° C.]: 4.2 CPTP-31 6.00% ε_(⊥) [1 kHz, 20° C.]: 6.9 CPTP-32 3.50% K₃ [pN, 20° C.]: 16.9 PPTUI-3-2 17.50% K₃/K₁ [20° C.]: 1.30 PTP-3O2FF 12.00% γ₁ [mPa · s, 20° C.]: 145 PTP-5O2FF 12.00% V₀ [20° C., V]: 2.65 CPTP-3O2FF 5.00% CPTP-5O2FF 5.00% H40: Nematic Host-Mixture

Y-4O-O4 13.00% Clearing point [° C.]: 100 CPY-3-O2 7.00% Δn [589 nm, 20° C.]: 0.2139 CCP-V-1 13.00% Δε [1 kHz, 20° C.]: −3.4 CCP-V2-1 10.00% ε_(∥) [1 kHz, 20° C.]: 4.2 BCH-32 5.00% ε_(⊥) [1 kHz, 20° C.]: 7.6 PPTUI-3-2 16.00% K₃ [pN, 20° C.]: 22.0 CCPC-33 2.00% K₃/K₁ [20° C.]: 1.28 PTP-3O2FF 12.00% V₀ [20° C., V]: 2.68 PTP-5O2FF 12.00% CPTP-3O2FF 5.00% CPTP-5O2FF 5.00% H41: Nematic Host-Mixture

Y-4O-O4 13.00% Clearing point [° C.]: 100 CPY-3-O2 7.00% Δn [589 nm, 20° C.]: 0.2103 CCP-V-1 13.00% Δε [1 kHz, 20° C.]: −3.4 CCP-V2-1 11.00% ε_(∥) [1 kHz, 20° C.]: 4.2 BCH-32 5.50% ε_(⊥) [1 kHz, 20° C.]: 7.6 PPTUI-3-2 14.50% K₃ [pN, 20° C.]: 22.0 CCPC-33 2.00% K₃/K₁ [20° C.]: 1.24 PTP-3O2FF 12.00% γ₁ [mPa · s, 20° C.]: 230 PTP-5O2FF 12.00% V₀ [20° C., V]: 2.67 CPTP-3O2FF 5.00% CPTP-5O2FF 5.00% H42: Nematic Host-Mixture

Y-4O-O4 13.00% Clearing point [° C.]: 100 CPY-3-O2 6.00% Δn [589 nm, 20° C.]: 0.2091 CC-4-V 3.00% Δε [1 kHz, 20° C.]: −3.3 CCP-V-1 12.50% ε_(∥) [1 kHz, 20° C.]: 4.2 CCP-V2-1 5.50% ε_(⊥) [1 kHz, 20° C.]: 7.5 BCH-32 5.50% K₃ [pN, 20° C.]: 21.7 PPTUI-3-2 15.50% K₃/K₁ [20° C.]: 1.27 CCPC-33 5.00% γ₁ [mPa · s, 20° C.]: 228 PTP-3O2FF 12.00% V₀ [20° C., V]: 2.68 PTP-5O2FF 12.00% CPTP-3O2FF 5.00% CPTP-5O2FF 5.00% H43: Nematic Host-Mixture

Y-4O-O4 10.00% Clearing point [° C.]: 103 CC-4-V 15.00% Δn [589 nm, 20° C.]: 0.1613 CC-3-V1 3.00% Δε [1 kHz, 20° C.]: −2.0 CCP-V-1 13.00% ε_(∥) [1 kHz, 20° C.]: 3.6 CCP-V2-1 13.00% ε_(⊥) [1 kHz, 20° C.]: 5.6 BCH-32 5.00% K₃ [pN, 20° C.]: 19.3 PPTUI-3-2 9.00% K₃/K₁ [20° C.]: 1.19 PTP-3O2FF 8.00% V₀ [20° C., V]: 3.31 PTP-5O2FF 8.00% CPTP-3O2FF 5.00% CPTP-5O2FF 5.00% CCPC-33 4.00% CCPC-34 2.00% H44: Nematic Host-Mixture

Y-4O-O4 10.00% Clearing point [° C.]: 105 CC-4-V 8.00% Δn [589 nm, 20° C.]: 0.2201 CCP-V-1 12.00% Δε [1 kHz, 20° C.]: −1.9 CCP-V2-1 10.00% ε_(∥) [1 kHz, 20° C.]: 3.9 BCH-32 5.00% ε_(⊥) [1 kHz, 20° C.]: 5.8 PPTUI-3-2 15.00% K₃ [pN, 20° C.]: 20.9 PPTUI-3-4 13.00% K₃/K₁ [20° C.]: 1.20 PTP-3O2FF 12.00% V₀ [20° C., V]: 3.51 PTP-5O2FF 5.00% CPTP-3O2FF 5.00% CPTP-5O2FF 5.00% H45: Nematic Host-Mixture

Y-4O-O4 10.00% Clearing point [° C.]: 100 CCY-3-O2 6.00% Δn [589 nm, 20° C.]: 0.1608 CCY-3-O3 6.00% Δε [1 kHz, 20° C.]: −4.2 CCY-4-O2 6.00% ε_(||) [1 kHz, 20° C.]: 4.1 CPY-2-O2 5.00% ε_(⊥) [1 kHz, 20° C.]: 8.3 CC-4-V 7.00% K₃ [pN, 20° C.]: 19.4 CCP-V-1 13.00% K₃/K₁ [20° C.]: 1.13 CCP-V2-1 13.00% V₀ [20° C., V]: 2.26 PPTUI-3-2 2.00% PTP-3O2FF 11.00% PTP-5O2FF 11.00% CPTP-3O2FF 5.00% CPTP-5O2FF 5.00% H46: Nematic Host-Mixture

Y-4O-O4 10.00% Clearing point [° C.]: 102 CC-4-V 11.50% Δn [589 nm, 20° C.]: 0.1604 CC-3-V1 8.00% Δε [1 kHz, 20° C.]: −2.0 CCP-V-1 13.00% ε_(||) [1 kHz, 20° C.]: 3.6 CCP-V2-1 13.00% ε_(⊥) [1 kHz, 20° C.]: 5.6 BCH-32 5.00% K₃ [pN, 20° C.]: 19.5 PPTUI-3-2 8.50% K₃/K₁ [20° C.]: 1.16 PTP-3O2FF 8.00% γ₁ [mPa · s, 20° C.]: 143 PTP-5O2FF 8.00% V₀ [20° C., V]: 3.34 CPTP-3O2FF 5.00% CPTP-5O2FF 5.00% CCPC-33 5.00% H47: Nematic Host-Mixture

Y-4O-O4 10.00% Clearing point [° C.]: 101 CC-4-V 9.50% Δn [589 nm, 20° C.]: 0.2207 CCP-V-1 10.00% Δε [1 kHz, 20° C.]: −1.9 CCP-V2-1 9.00% ε_(||) [1 kHz, 20° C.]: 4.0 BCH-32 5.00% ε_(⊥) [1 kHz, 20° C.]: 5.9 PPTUI-3-2 15.50% K₃ [pN, 20° C.]: 20.2 PPTUI-3-4 13.00% K₃/K₁ [20° C.]: 1.20 PTP-3O2FF 9.00% V₀ [20° C., V]: 3.45 PTP-5O2FF 9.00% CPTP-3O2FF 5.00% CPTP-5O2FF 5.00% H48: Nematic Host-Mixture

Y-4O-O4 10.00% Clearing point [° C.]: 101 CC-4-V 8.50% Δn[589 nm, 20° C.]: 0.2209 CCP-V-1 12.00% Δε [1 kHz, 20° C.]: −2.0 CCP-V2-1 8.00% ε_(||) [1 kHz, 20° C.]: 4.0 BCH-32 5.00% ε_(⊥) [1 kHz, 20° C.]: 6.0 PPTUI-3-2 18.00% K₃ [pN, 20° C.]: 20.5 PPTUI-3-4 9.50% K₃/K₁ [20° C.]: 1.23 PTP-3O2FF 9.50% V₀ [20° C., V]: 3.38 PTP-5O2FF 9.50% CPTP-3O2FF 5.00% CPTP-5O2FF 5.00% H49: Nematic Host-Mixture

Y-4O-O4 10.00% Clearing point [° C.]: 103 CCY-3-O2 6.00% Δn [589 nm, 20° C.]: 0.2184 CCY-3-O3 6.00% Δε [1 kHz, 20° C.]: −4.2 CCY-4-O2 6.00% ε_(||) [1 kHz, 20° C.]: 4.3 CPY-2-O2 5.00% ε_(⊥) [1 kHz, 20° C.]: 8.5 CC-4-V 3.00% K₃ [pN, 20° C.]: 22.1 CCP-V-1 7.00% K₃/K₁ [20° C.]: 1.23 BCH-32 5.00% V₀ [20° C., V]: 2.41 PPTUI-3-2 18.00% PTP-3O2FF 12.00% PTP-5O2FF 12.00% CPTP-3O2FF 5.00% CPTP-5O2FF 5.00% H50: Nematic Host-Mixture

Y-4O-O4 10.00% Clearing point [° C.]: 102 CCY-3-O2 6.00% Δn [589 nm, 20° C.]: 0.1601 CCY-3-O3 6.00% Δε [1 kHz, 20° C.]: −4.0 CCY-4-O2 5.50% ε_(||) [1 kHz, 20° C.]: 4.0 CPY-2-O2 5.00% ε_(⊥) [1 kHz, 20° C.]: 8.0 CC-4-V 7.50% K₃ [pN, 20° C.]: 19.1 CCP-V-1 12.00% K₃/K₁ [20° C.]: 1.14 CCP-V2-1 12.00% γ₁ [mPa · s, 20° C.]: 201 BCH-32 4.00% V₀ [20° C., V]: 2.32 PPTUI-3-2 2.00% PTP-3O2FF 10.00% PTP-5O2FF 10.00% CPTP-3O2FF 5.00% CPTP-5O2FF 5.00% H51: Nematic Host-Mixture

Y-4O-O4 10.00% Clearing point [° C.]: 102 CCY-3-O2 6.00% Δn [589 nm, 20° C.]: 0.2197 CCY-3-O3 6.00% Δε [1 kHz, 20° C.]: −4.1 CCY-4-O2 4.50% ε_(||) [1 kHz, 20° C.]: 4.3 CPY-2-O2 5.00% ε_(⊥) [1 kHz, 20° C.]: 8.4 CC-4-V 4.00% K₃ [pN, 20° C.]: 21.7 CCP-V-1 6.50% K₃/K₁ [20° C.]: 1.25 BCH-32 5.00% γ₁ [mPa · s, 20° C.]: 285 PPTUI-3-2 19.00% V₀ [20° C., V]: 2.43 PTP-3O2FF 12.00% PTP-5O2FF 12.00% CPTP-3O2FF 5.00% CPTP-5O2FF 5.00% H52: Nematic Host-Mixture

Y-4O-O4 10.00% Clearing point [° C.]: 102 CC-4-V 8.00% Δn [589 nm, 20° C.]: 0.2203 CCP-V-1 13.00% Δε [1 kHz, 20° C.]: −2.0 CCP-V2-1 8.00% ε_(||) [1 kHz, 20° C.]: 4.0 BCH-32 5.00% ε_(⊥) [1 kHz, 20° C.]: 6.0 PPTUI-3-2 18.00% K₃ [pN, 20° C.]: 20.3 PPTUI-3-4 9.00% K₃/K₁ [20° C.]: 1.20 PTP-3O2FF 9.50% γ₁ [mPa · s, 20° C.]: 190 PTP-5O2FF 9.50% V₀ [20° C., V]: 3.38 CPTP-3O2FF 5.00% CPTP-5O2FF 5.00% H53: Nematic Host-Mixture

Y-4O-O4 4.00% Clearing point [° C.]: 101 CPY-3-O2 5.00% Δn [589 nm, 20° C.]: 0.2000 CC-3-V 15.00% Δε [1 kHz, 20° C.]: −2.1 CC-4-V 5.00% ε_(||) [1 kHz, 20° C.]: 3.7 CCP-V-1 12.00% ε_(⊥) [1 kHz, 20° C.]: 5.8 CCP-V2-1 4.00% K₃ [pN, 20° C.]: 20.6 BCH-32 5.00% K₃/K₁ [20° C.]: 1.26 PPTUI-3-2 16.00% γ₁ [mPa · s, 20° C.]: 157 PTP-3O2FF 12.00% V₀ [20° C., V]: 3.32 PTP-5O2FF 12.00% CPTP-3O2FF 5.00% CPTP-5O2FF 5.00% H54: Nematic Host-Mixture

Y-4O-O4 4.00% Clearing point [° C.]: 101 CPY-3-O2 4.00% Δn [589 nm, 20° C.]: 0.1976 CC-3-V 15.00% Δε [1 kHz, 20° C.]: −2.0 CC-4-V 5.00% ε_(||) [1 kHz, 20° C.]: 3.7 CCP-V-1 13.00% ε_(⊥) [1 kHz, 20° C.]: 5.7 CCP-V2-1 4.50% K₃ [pN, 20° C.]: 20.5 BCH-32 5.00% K₃/K₁ [20° C.]: 1.25 PPTUI-3-2 15.50% γ₁ [mPa · s, 20° C.]: 150 PTP-3O2FF 12.00% V₀ [20° C., V]: 3.35 PTP-5O2FF 12.00% CPTP-3O2FF 5.00% CPTP-5O2FF 5.00% H55: Nematic Host-Mixture

Y-4O-O4 8.00% Clearing point [° C.]: 104 CPY-2-O2 5.00% Δn [589 nm, 20° C.]: 0.1952 CPY-3-O2 5.00% Δε [1 kHz, 20° C.]: −1.1 CC-3-V 15.00% ε_(||) [1 kHz, 20° C.]: 3.6 CC-4-V 12.00% ε_(⊥) [1 kHz, 20° C.]: 4.7 CCP-V-1 7.00% BCH-32 5.00% PPTUI-3-2 17.00% PPTUI-3-4 16.00% CPTP-3O2FF 5.00% CPTP-5O2FF 5.00% H56: Nematic Host-Mixture

Y-4O-O4 10.00% Clearing point [° C.]: 101 CPY-2-O2 8.00% Δn [589 nm, 20° C.]: 0.1995 CPY-3-O2 8.00% Δε [1 kHz, 20° C.]: −1.6 CC-3-V 15.00% ε_(||) [1 kHz, 20° C.]: 3.9 CC-4-V 9.50% ε_(⊥) [1 kHz, 20° C.]: 5.5 CCP-V-1 2.00% K₃ [pN, 20° C.]: 18.6 BCH-32 5.00% K₃/K₁ [20° C.]: 1.18 PPTUI-3-2 17.00% γ₁ [mPa · s, 20° C.]: 153 PPTUI-3-4 15.50% V₀ [20° C., V]: 3.52 CPTP-3O2FF 5.00% CPTP-5O2FF 5.00% H57: Nematic Host-Mixture

Y-4O-O4 14.00% Clearing point [° C.]: 102 CCY-3-O2 6.00% Δn [589 nm, 20° C.]: 0.1457 CCY-3-O3 6.00% Δε [1 kHz, 20° C.]: −4.1 CCY-4-O2 6.00% ε_(||) [1 kHz, 20° C.]: 4.2 CPY-2-O2 8.00% ε_(⊥) [1 kHz, 20° C.]: 8.3 CPY-3-O2 8.00% CC-4-V 10.00% CCP-V-1 12.00% CCP-V2-1 9.00% PPTUI-3-2 6.00% PTP-3O2FF 5.00% CPTP-3O2FF 5.00% CPTP-5O2FF 5.00% H58: Nematic Host-Mixture

Y-4O-O4 12.00% Clearing point [° C.]: 100 CCY-3-O2 6.00% Δn [589 nm, 20° C.]: 0.1476 CCY-3-O3 6.00% Δε [1 kHz, 20° C.]: −4.2 CCY-4-O2 5.00% ε_(||) [1 kHz, 20° C.]: 4.0 CPY-2-O2 5.00% ε_(⊥) [1 kHz, 20° C.]: 8.2 CPY-3-O2 5.00% K₃ [pN, 20° C.]: 18.5 CC-4-V 9.00% K₃/K₁ [20° C.]: 1.09 CCP-V-1 11.00% γ₁ [mPa · s, 20° C.]: 191 CCP-V2-1 11.00% V₀ [20° C., V]: 2.21 BCH-32 5.00% PTP-3O2FF 7.50% PTP-5O2FF 7.50% CPTP-3O2FF 5.00% CPTP-5O2FF 5.00% H59: Nematic Host-Mixture

Y-4O-O4 4.00% Clearing point [° C.]: 100 CPY-3-O2 8.00% Δn [589 nm, 20° C.]: 0.1998 CC-3-V 15.00% Δε [1 kHz, 20° C.]: −2.0 CC-4-V 9.00% ε_(||) [1 kHz, 20° C.]: 3.7 CCP-V-1 10.00% ε_(⊥) [1 kHz, 20° C.]: 5.7 BCH-32 5.00% K₃ [pN, 20° C.]: 20.0 PPTUI-3-2 19.00% K₃/K₁ [20° C.]: 1.25 PTP-3O2FF 10.00% γ₁ [mPa · s, 20° C.]: 152 PTP-5O2FF 10.00% V₀ [20° C., V]: 3.37 CPTP-3O2FF 5.00% CPTP-5O2FF 5.00% H60: Nematic Host-Mixture

Y-4O-O4 4.00% Clearing point [° C.]: 99 CPY-3-O2 5.50% Δn [589 nm, 20° C.]: 0.2201 CC-3-V 15.00% Δε [1 kHz, 20° C.]: −2.0 CC-4-V 7.00% ε_(∥) [1 kHz, 20° C.]: 3.8 CCP-V-1 5.00% ε_(⊥) [1 kHz, 20° C.]: 5.8 BCH-32 5.00% PPTUI-3-2 19.00% PPTUI-3-4 5.50% PTP-3O2FF 12.00% PTP-5O2FF 12.00% CPTP-3O2FF 5.00% CPTP-5O2FF 5.00% H61: Nematic Host-Mixture

Y-4O-O4 2.00% Clearing point [° C.]: 100 CCY-3-O2 3.00% Δn [589 nm, 20° C.]: 0.1983 CPY-3-O2 5.00% Δε [1 kHz, 20° C.]: −2.0 CC-3-V 15.00% ε_(∥) [1 kHz, 20° C.]: 3.6 CC-4-V 12.50% ε_(⊥) [1 kHz, 20° C.]: 5.6 CCP-V2-1 6.50% K₃ [pN, 20° C.]: 19.7 BCH-32 5.00% K₃/K₁ [20° C.]: 1.14 PPTUI-3-2 17.00% γ₁ [mPa · s, 20° C.]: 149 PTP-3O2FF 12.00% V₀ [20° C., V]: 3.30 PTP-5O2FF 12.00% CPTP-3O2FF 5.00% CPTP-5O2FF 5.00% H62: Nematic Host-Mixture

Y-4O-O4 6.00% Clearing point [° C.]: 100 CC-3-V 15.00% Δn [589 nm, 20° C.]: 0.2010 CC-5-V 8.00% Δε [1 kHz, 20° C.]: −2.1 CCP-V-1 11.50% ε_(∥) [1 kHz, 20° C.]: 3.8 BCH-32 5.00% ε_(⊥) [1 kHz, 20° C.]: 5.9 PPTUI-3-2 16.50% K₃ [pN, 20° C.]: 20.3 PTP-3O2FF 10.00% K₃/K₁ [20° C.]: 1.18 PTP-5O2FF 10.00% γ₁ [mPa · s, 20° C.]: 154 CPTP-3O2FF 9.00% V₀ [20° C., V]: 3.26 CPTP-5O2FF 9.00% H63: Nematic Host-Mixture

Y-4O-O4 2.00% Clearing point [° C.]: 99 CC-3-V 25.00% Δn [589 nm, 20° C.]: 0.1985 CC-4-V 6.00% Δε [1 kHz, 20° C.]: −0.6 CCP-V-1 12.00% ε_(∥) [1 kHz, 20° C.]: 3.4 BCH-32 5.00% ε_(⊥) [1 kHz, 20° C.]: 4.0 PPTUI-3-2 20.00% PPTUI-3-4 10.50% PTP-3O2FF 7.50% PTP-5O2FF 7.50% CPTP-3O2FF 4.50% H64: Nematic Host-Mixture

Y-4O-O4 4.00% Clearing point [° C.]: 100 CCY-3-O2 6.00% Δn [589 nm, 20° C.]: 0.1998 CCY-3-O3 3.50% Δε [1 kHz, 20° C.]: −3.0 CPY-3-O2 3.00% ε_(∥) [1 kHz, 20° C.]: 3.8 CC-3-V 25.00% ε_(⊥) [1 kHz, 20° C.]: 6.8 BCH-32 5.00% PPTUI-3-2 13.50% PTP-3O2FF 12.00% PTP-5O2FF 12.00% CPTP-3O2FF 8.00% CPTP-5O2FF 8.00% H65: Nematic Host-Mixture

Y-4O-O4 2.00% Clearing point [° C.]: 100 CC-3-V 25.00% Δn [589 nm, 20° C.]: 0.2006 CC-4-V 10.00% Δε [1 kHz, 20° C.]: −0.5 CCP-V-1 6.50% ε_(∥) [1 kHz, 20° C.]: 3.4 BCH-32 5.00% ε_(⊥) [1 kHz, 20° C.]: 3.9 PPTUI-3-2 20.00% PPTUI-3-4 12.00% PTP-3O2FF 12.00% CPTP-3O2FF 7.50% H66: Nematic Host-Mixture

Y-4O-O4 4.00% Clearing point [° C.]: 100 CCY-3-O2 6.00% Δn [589 nm, 20° C.]: 0.1793 CPY-3-O2 4.50% Δε [1 kHz, 20° C.]: −2.9 CC-3-V 25.00% ε_(∥) [1 kHz, 20° C.]: 3.7 CCP-V-1 5.00% ε_(⊥) [1 kHz, 20° C.]: 6.6 CCP-V2-1 5.00% BCH-32 5.00% PPTUI-3-2 5.50% PTP-3O2FF 12.00% PTP-5O2FF 12.00% CPTP-3O2FF 8.00% CPTP-5O2FF 8.00% H67: Nematic Host-Mixture

Y-4O-O4 2.00% Clearing point [° C.]: 100 CC-3-V 25.00% Δn [589 nm, 20° C.]: 0.1995 CC-4-V 7.50% Δε [1 kHz, 20° C.]: −0.6 CCP-V-1 9.50% ε_(∥) [1 kHz, 20° C.]: 3.4 BCH-32 5.00% ε_(⊥) [1 kHz, 20° C.]: 4.0 PPTUI-3-2 20.00% PPTUI-3-4 11.00% PTP-3O2FF 7.00% PTP-5O2FF 7.00% CPTP-3O2FF 6.00% H68: Nematic Host-Mixture

Y-4O-O4 3.50% Clearing point [° C.]: 100 CCY-3-O2 6.00% Δn [589 nm, 20° C.]: 0.1796 CPY-3-O2 4.50% Δε [1 kHz, 20° C.]: −2.9 CC-3-V 25.00% ε_(∥) [1 kHz, 20° C.]: 3.7 CC-4-V 4.00% ε_(⊥) [1 kHz, 20° C.]: 6.6 CCP-V-1 4.50% BCH-32 5.00% PPTUI-3-2 5.50% PTP-3O2FF 11.00% PTP-5O2FF 11.00% CPTP-3O2FF 10.00% CPTP-5O2FF 10.00% H69: Nematic Host-Mixture

Y-4O-O4 2.00% Clearing point [° C.]: 100 CC-3-V 25.00% Δn [589 nm, 20° C.]: 0.1803 CC-4-V 8.00% Δε [1 kHz, 20° C.]: −0.7 CCP-V-1 12.00% ε_(∥) [1 kHz, 20° C.]: 3.3 CCP-V2-1 5.00% ε_(⊥) [1 kHz, 20° C.]: 4.0 BCH-32 5.00% PPTUI-3-2 20.00% PPTUI-3-4 3.00% PTP-3O2FF 7.00% PTP-5O2FF 7.00% CPTP-3O2FF 6.00% H70: Nematic Host-Mixture

Y-4O-O4 3.00% Clearing point [° C.]: 100 CCY-3-O2 5.00% Δn [589 nm, 20° C.]: 0.1996 CPY-3-O2 5.00% Δε [1 kHz, 20° C.]: −2.9 CC-3-V 25.00% ε_(∥) [1 kHz, 20° C.]: 3.8 CC-4-V 4.00% ε_(⊥) [1 kHz, 20° C.]: 6.7 BCH-32 2.00% PPTUI-3-2 12.00% PTP-3O2FF 12.00% PTP-5O2FF 12.00% CPTP-3O2FF 10.00% CPTP-5O2FF 10.00% H71: Nematic Host-Mixture

Y-4O-O4 2.50% Clearing point [° C.]: 100 CCY-3-O2 5.50% Δn [589 nm, 20° C.]: 0.1787 CPY-3-O2 5.00% Δε [1 kHz, 20° C.]: −2.9 CC-3-V 25.00% ε_(∥) [1 kHz, 20° C.]: 3.6 CC-4-V 5.50% ε_(⊥) [1 kHz, 20° C.]: 6.5 CCP-V-1 3.50% BCH-32 5.00% PPTUI-3-2 4.00% PTP-3O2FF 12.00% PTP-5O2FF 12.00% CPTP-3O2FF 10.00% CPTP-5O2FF 10.00% H72: Nematic Host-Mixture

Y-4O-O4 2.00% Clearing point [° C.]: 100 CC-3-V 25.00% Δn [589 nm, 20° C.]: 0.1798 CC-4-V 8.00% Δε [1 kHz, 20° C.]: −0.6 CCP-V-1 11.00% ε_(∥) [1 kHz, 20° C.]: 3.3 CCP-V2-1 6.50% ε_(⊥) [1 kHz, 20° C.]: 3.9 BCH-32 5.00% PPTUI-3-2 20.00% PPTUI-3-4 3.00% PTP-3O2FF 7.00% PTP-5O2FF 7.00% CPTP-3O2FF 5.50% H73: Nematic Host-Mixture

Y-4O-O4 5.00% Clearing point [° C.]: 100 CCY-3-O2 2.00% Δn [589 nm, 20° C.]: 0.2211 CPY-3-O2 6.00% Δε [1 kHz, 20° C.]: −3.0 CC-3-V 24.00% ε_(∥) [1 kHz, 20° C.]: 4.0 PPTUI-3-2 19.00% ε_(⊥) [1 kHz, 20° C.]: 7.0 PTP-3O2FF 12.00% PTP-5O2FF 12.00% CPTP-3O2FF 10.00% CPTP-5O2FF 10.00% H74: Nematic Host-Mixture

Y-4O-O4 2.00% Clearing point [° C.]: 100 CC-3-V 25.00% Δn [589 nm, 20° C.]: 0.2215 CC-4-V 8.00% Δε [1 kHz, 20° C.]: −0.5 BCH-32 5.00% ε_(∥) [1 kHz, 20° C.]: 3.5 PPTUI-3-2 20.00% ε_(⊥) [1 kHz, 20° C.]: 4.0 PPTUI-3-4 19.50% PTP-3O2FF 7.00% PTP-5O2FF 7.00% CPTP-3O2FF 6.50% H75: Nematic Host-Mixture

Y-4O-O4 3.00% Clearing point [° C.]: 100 CC-3-V 18.00% Δn [589 nm, 20° C.]: 0.2003 CC-4-V 14.00% Δε [1 kHz, 20° C.]: −2.1 BCH-32 4.50% ε_(∥) [1 kHz, 20° C.]: 3.7 CPY-3-O2 5.00% ε_(⊥) [1 kHz, 20° C.]: 5.8 PTP-3O2FF 10.00% K₃ [pN, 20° C.]: 19.9 PTP-5O2FF 9.00% K₃/K₁ [20° C.]: 1.16 CPTP-3O2FF 10.00% V₀ [20° C., V]: 3.21 CPTP-5O2FF 10.00% PPTUI-3-2 16.50% H76: Nematic Host-Mixture

Y-4O-O4 15.00% Clearing point [° C.]: 81 CY-3-O2 15.00% Δn [589 nm, 20° C.]: 0.1470 CY-3-O4 4.00% Δε [1 kHz, 20° C.]: −8.2 CCY-3-O2 6.50% ε_(∥) [1 kHz, 20° C.]: 5.3 CCY-3-O3 6.50% ε_(⊥) [1 kHz, 20° C.]: 13.5 CLY-3-O2 6.50% K₃ [pN, 20° C.]: 17.0 CLY-3-O3 6.00% K₃/K₁ [20° C.]: 1.17 CPY-2-O2 10.00% V₀ [20° C., V]: 1.51 CPY-3-O2 10.00% PTP-3O2FF 4.50% CPTP-3O2FF 8.00% CPTP-5O2FF 8.00% H77: Nematic Host-Mixture

Y-4O-O4 15.00% Clearing point [° C.]: 80 CY-3-O2 10.00% Δn [589 nm, 20° C.]: 0.1420 CY-3-O4 10.00% Δε [1 kHz, 20° C.]: −8.1 CCY-3-O2 6.50% ε_(∥) [1 kHz, 20° C.]: 5.3 CCY-3-O3 6.50% ε_(⊥) [1 kHz, 20° C.]: 13.4 CCY-4-O2 6.00% K₃ [pN, 20° C.]: 17.0 CLY-3-O2 6.00% K₃/K₁ [20° C.]: 1.25 CPY-2-O2 10.00% V₀ [20° C., V]: 1.52 CPY-3-O2 10.00% PTP-3O2FF 4.00% CPTP-3O2FF 8.00% CPTP-5O2FF 8.00% H78: Nematic Host-Mixture

Y-4O-O4 3.00% Clearing point [° C.]: 100 CCY-3-O2 6.00% Δn [589 nm, 20° C.]: 0.1798 CPY-3-O2 5.00% Δε [1 kHz, 20° C.]: −3.0 CC-3-V 25.00% ε_(∥) [1 kHz, 20° C.]: 3.6 CC-4-V 5.00% ε_(⊥) [1 kHz, 20° C.]: 6.6 CCP-V-1 3.00% γ₁ [mPa · s, 20° C.]: 155 BCH-32 5.00% PPTUI-3-2 5.00% PTP-3O2FF 11.50% PTP-5O2FF 11.50% CPTP-3O2FF 10.00% CPTP-5O2FF 10.00% H79: Nematic Host-Mixture

Y-4O-O4 5.00% Clearing point [° C.]: 100 CCY-3-O2 3.00% Δn [589 nm, 20° C.]: 0.2203 CPY-3-O2 5.00% Δε [1 kHz, 20° C.]: −3.0 CC-3-V 24.00% ε_(∥) [1 kHz, 20° C.]: 4.0 PPTUI-3-2 19.00% ε_(⊥) [1 kHz, 20° C.]: 7.0 PTP-3O2FF 12.00% γ₁ [mPa · s, 20° C.]: 184 PTP-5O2FF 12.00% CPTP-3O2FF 10.00% CPTP-5O2FF 10.00% H80: Nematic Host-Mixture

Y-4O-O4 12.00% Clearing point [° C.]: 70 CY-3-O2 15.00% Δn [589 nm, 20° C.]: 0.1423 PY-1-O4 11.00% Δε [1 kHz, 20° C.]: −8.1 PY-3-O2 6.00% ε_(∥) [1 kHz, 20° C.]: 5.4 CCY-3-O2 6.00% ε_(⊥) [1 kHz, 2000]: 13.5 CCY-3-O3 6.00% K₃ [pN, 20° C.]: 15.8 CCY-4-O2 6.00% K₃/K₁ [20° C.]: 1.24 CLY-3-O2 5.00% V₀ [20° C., V]: 1.46 CPY-2-O2 10.00% CPY-3-O2 10.00% CPTP-3O2FF 6.50% CPTP-5O2FF 6.50% H81: Nematic Host-Mixture

Y-4O-O4 15.00% Clearing point [° C.]: 70 CY-3-O2 15.00% Δn [589 nm, 20° C.]: 0.1429 CY-3-O4 11.00% Δε [1 kHz, 20° C.]: −7.9 CCY-3-O2 6.00% ε_(∥) [1 kHz, 20° C.]: 5.5 CCY-3-O3 6.00% ε_(⊥) [1 kHz, 20° C.]: 13.4 CCY-4-O2 4.00% K₃ [pN, 20° C.]: 15.0 CPY-2-O2 10.00% K₃/K₁ [20° C.]: 1.21 CPY-3-O2 10.00% V₀ [20° C., V]: 1.45 PTP-3O2FF 3.00% CPTP-3O2FF 10.00% CPTP-5O2FF 10.00% H82: Nematic Host-Mixture

Y-4O-O4 3.50% Clearing point [° C.]: 100 CCY-3-O2 4.50% Δn [589 nm, 20° C.]: 0.1999 CPY-3-O2 5.00% Δε [1 kHz, 20° C.]: −3.0 CC-3-V 25.00% ε_(∥) [1 kHz, 20° C.]: 3.8 CC-4-V 3.00% ε_(⊥) [1 kHz, 20° C.]: 6.8 BCH-32 3.50% γ₁ [mPa · s, 20° C.]: 169 PPTUI-3-2 11.50% PTP-3O2FF 12.00% PTP-5O2FF 12.00% CPTP-3O2FF 10.00% CPTP-5O2FF 10.00% H83: Nematic Host-Mixture

Y-4O-O4 3.50% Clearing point [° C.]: 100 PYP-2-3 13.00% Δn [589 nm, 20° C.]: 0.2189 CPY-3-O2 4.50% Δε [1 kHz, 20° C.]: −2.9 CC-3-V 24.00% ε_(∥) [1 kHz, 20° C.]: 3.9 PPTUI-3-2 13.00% ε_(⊥) [1 kHz, 20° C.]: 6.8 PTP-3O2FF 11.00% PTP-5O2FF 11.00% CPTP-3O2FF 10.00% CPTP-5O2FF 10.00% H84: Nematic Host-Mixture

Y-4O-O4 3.50% Clearing point [° C.]: 100 PYP-2-3 12.00% Δn [589 nm, 20° C.]: 0.2205 CPY-3-O2 5.00% Δε [1 kHz, 20° C.]: −3.0 CC-3-V 23.50% ε_(∥) [1 kHz, 20° C.]: 3.9 PPTUI-3-2 13.00% ε_(⊥) [1 kHz, 20° C.]: 6.9 PTP-3O2FF 11.50% γ₁ [mPa · s, 20° C.]: 188 PTP-5O2FF 11.50% CPTP-3O2FF 10.00% CPTP-5O2FF 10.00% H85: Nematic Host-Mixture

Y-4O-O4 2.00% Clearing point [° C.]: 100 CC-3-V 25.00% Δn [589 nm, 20° C.]: 0.1799 CC-4-V 5.50% Δε [1 kHz, 20° C.]: −0.7 CCP-V-1 12.50% ε_(∥) [1 kHz, 20° C.]: 3.3 CCP-V2-1 8.00% ε_(⊥) [1 kHz, 20° C.]: 4.0 BCH-32 5.00% PPTUI-3-2 20.00% PPTUI-3-4 2.00% PTP-3O2FF 8.00% PTP-5O2FF 8.00% CPTP-3O2FF 4.00% H86: Nematic Host-Mixture

Y-4O-O4 3.00% Clearing point [° C.]: 99 CC-3-V 20.00% Δn [589 nm, 20° C.]: 0.1992 CC-5-V 14.00% Δε [1 kHz, 20° C.]: −2.1 BCH-32 3.00% ε_(∥) [1 kHz, 20° C.]: 3.6 CPY-2-O2 4.00% ε_(⊥) [1 kHz, 20° C.]: 5.7 PTP-3O2FF 10.00% K₃ [pN, 20° C.]: 20.5 PTP-5O2FF 9.00% K₃/K₁ [20° C.]: 1.23 CPTP-3O2FF 10.00% γ₁ [mPa · s, 20° C.]: 149 CPTP-5O2FF 10.00% V₀ [20° C., V]: 3.30 PPTUI-3-2 17.00% H87: Nematic Host-Mixture

Y-4O-O4 3.00% Clearing point [° C.]: 100 CC-3-V 33.00% Δn [589 nm, 20° C.]: 0.2009 BCH-32 3.00% Δε [1 kHz, 20° C.]: −2.2 CPY-3-O2 5.00% ε_(∥) [1 kHz, 20° C.]: 3.6 PTP-3O2FF 10.00% ε_(⊥) [1 kHz, 20° C.]: 5.8 PTP-5O2FF 9.00% K₃ [pN, 20° C.]: 21.0 CPTP-3O2FF 10.00% K₃/K₁ [20° C.]: 1.30 CPTP-5O2FF 10.00% V₀ [20° C., V]: 3.29 PPTUI-3-2 17.00% H88: Nematic Host-Mixture

Y-4O-O4 5.00% Clearing point [° C.]: 101 CCY-3-O2 6.00% Δn [589 nm, 20° C.]: 0.2033 CCY-3-O3 6.00% Δε [1 kHz, 20° C.]: −3.0 CC-3-V 20.50% ε_(∥) [1 kHz, 20° C.]: 3.9 CCP-V-1 3.50% ε_(⊥) [1 kHz, 20° C.]: 6.9 BCH-32 5.00% PPTUI-3-2 15.00% PTP-3O2FF 12.00% PTP-5O2FF 12.00% CPTP-3O2FF 7.50% CPTP-5O2FF 7.50% H89: Nematic Host-Mixture

Y-4O-O4 2.00% Clearing point [° C.]: 102 PCH-301 5.00% Δn [589 nm, 20° C.]: 0.2018 CC-3-V 25.00% Δε [1 kHz, 20° C.]: −0.7 CCP-V-1 9.00% ε_(∥) [1 kHz, 20° C.]: 3.4 CCP-V2-1 4.50% ε_(⊥) [1 kHz, 20° C.]: 4.1 BCH-32 5.00% PPTUI-3-2 20.00% PPTUI-3-4 9.50% PTP-3O2FF 7.00% PTP-5O2FF 7.00% CPTP-3O2FF 6.00% H90: Nematic Host-Mixture

Y-4O-O4 5.00% Clearing point [° C.]: 100 CCY-3-O2 6.00% Δn [589 nm, 20° C.]: 0.1995 CCY-3-O3 6.00% Δε [1 kHz, 20° C.]: −3.0 CC-3-V 21.50% ε_(∥) [1 kHz, 20° C.]: 3.9 CCP-V-1 3.50% ε_(⊥) [1 kHz, 20° C.]: 6.9 BCH-32 5.00% PPTUI-3-2 14.00% PTP-3O2FF 12.00% PTP-5O2FF 12.00% CPTP-3O2FF 7.50% CPTP-5O2FF 7.50% H91: Nematic Host-Mixture

Y-4O-O4 2.00% Clearing point [° C.]: 100 PCH-301 4.50% Δn [589 nm, 20° C.]: 0.1989 CC-3-V 25.00% Δε [1 kHz, 20° C.]: −0.6 CCP-V-1 13.00% ε_(∥) [1 kHz, 20° C.]: 3.4 CCP-V2-1 2.00% ε_(⊥) [1 kHz, 20° C.]: 4.0 BCH-32 5.00% PPTUI-3-2 20.00% PPTUI-3-4 9.00% PTP-3O2FF 7.50% PTP-5O2FF 7.50% CPTP-3O2FF 4.50% H92: Nematic Host-Mixture

Y-4O-O4 3.00% Clearing point [° C.]: 100 PYP-2-3 10.00% Δn [589 nm, 20° C.]: 0.1603 PYP-2-4 10.00% Δε [1 kHz, 20° C.]: −0.7 CC-3-V 25.00% ε_(∥) [1 kHz, 20° C.]: 3.1 CCP-V-1 11.00% ε_(⊥) [1 kHz, 20° C.]: 3.8 CCP-V2-1 10.00% BCH-32 5.00% CVCP-1V-O1 5.00% PTP-3O2FF 3.00% CPTP-3O2FF 2.50% PTP-101 5.00% PTP-201 5.00% CPTP-301 5.00% PPTUI-3-2 0.50% stabilized with 0.01% of the compound of the formula

H93: Nematic Host-Mixture

CY-3-O2 15.00% Clearing point [° C.]: 91 CY-3-O4 20.00% Δn [589 nm, 20° C.]: 0.0909 CY-5-O2 10.00% ε_(∥) [1 kHz, 20° C.]: 4.1 CY-5-O4 7.00% ε_(⊥)[1 kHz, 20° C.]: 10.1 CCY-3-O2 6.50% Δε [1 kHz, 20° C.]: −6.0 CCY-3-O3 6.50% γ₁ [mPa · s, 20° C.]: 310 CCY-4-O2 6.50% CCY-5-O2 6.50% CPY-2-O2 3.00% CH-33 3.00% CH-35 3.00% CH-43 3.00% CCPC-33 5.00% CCPC-34 5.00% H94: Nematic Host-Mixture

CY-3-O2 15.00% Clearing point [° C.]: 91 CY-3-O4 20.00% Δn [589 nm, 20° C.]: 0.1099 CY-5-O2 10.00% ε_(∥) [1 kHz, 20° C.]: 4.2 CCY-3-O2 6.50% ε_(⊥) [1 kHz, 20° C.]: 10.3 CCY-3-O3 6.00% Δε [1 kHz, 20° C.]: −6.1 CCY-4-O2 6.00% γ₁ [mPa · s, 20° C.]: 297 CCY-5-O2 6.00% CPY-2-O2 8.00% CPY-3-O2 8.00% CC-4-V 2.50% CCP-V-1 3.50% CPTP-3-1 2.50% CCPC-33 4.00% CCPC-34 2.00% H95: Nematic Host-Mixture

CY-3-O2 15.00% Clearing point [° C.]: 91 CY-3-O4 20.00% Δn [589 nm, 20° C.]: 0.0897 CY-5-O2 6.00% ε_(∥) [1 kHz, 20° C.]: 3.7 CCY-3-O2 6.00% ε_(⊥) [1 kHz, 20° C.]: 8.0 CCY-3-O3 6.00% Δε [1 kHz, 20° C.]: −4.3 CCY-4-O2 6.00% γ₁ [mPa · s, 20° C.]: 204 CPY-2-O2 6.00% CC-4-V 15.00% CCP-V2-1 6.50% CCPC-33 4.50% CCPC-34 4.50% CCPC-35 4.50% H96: Nematic Host-Mixture

CY-3-O2 15.00% Clearing point [° C.]: 91 CY-3-O4 20.00% Δn [589 nm, 20° C.]: 0.1106 CCY-3-O2 6.00% ε_(∥) [1 kHz, 20° C.]: 3.9 CCY-3-O3 6.00% ε_(⊥) [1 kHz, 20° C.]: 8.4 CCY-4-O2 6.00% Δε [1 kHz, 20° C.]: −4.5 CCY-5-O2 2.00% γ₁ [mPa · s, 20° C.]: 202 CPY-2-O2 8.00% CPY-3-O2 8.00% CC-4-V 8.00% CCP-V-1 12.00% CCP-V2-1 5.00% CPTP-3-1 4.00% H97: Nematic Host-Mixture

CY-3-O2 15.00% Clearing point [° C.]: 95 CY-3-O4 20.00% Δn [589 nm, 20° C.]: 0.0974 CY-5-O2 8.50% ε_(∥) [1 kHz, 20° C.]: 4.1 CCY-3-O2 6.50% ε_(⊥) [1 kHz, 20° C.]: 9.9 CCY-3-O3 6.50% Δε [1 kHz, 20° C.]: −5.8 CCY-4-O2 6.50% K₁ [pN, 20° C.]: 14.3 CCY-5-O2 6.50% K₃ [pN, 20° C.]: 16.8 CPY-2-O2 7.50% V₀ [pN, 20° C.]: 1.79 CPY-3-O2 3.50% γ₁ [mPa · s, 20° C.]: 292 CC-4-V 6.00% CH-33 3.50% CCPC-33 5.00% CCPC-34 5.00% H98: Nematic Host-Mixture

CY-3-O2 15.00% Clearing point [° C.]: 95 CY-3-O4 20.00% Δn [589 nm, 20° C.]: 0.1126 CY-5-O2 2.00% ε_(∥) [1 kHz, 20° C.]: 4.0 CCY-3-O2 6.50% ε_(⊥) [1 kHz, 20° C.]: 9.8 CCY-3-O3 6.50% Δε [1 kHz, 20° C.]: −5.8 CCY-4-O2 6.50% K₁ [pN, 20° C.]: 15.1 CCY-5-O2 6.50% K₃ [pN, 20° C.]: 17.8 CPY-2-O2 8.00% V₀ [pN, 20° C.]: 1.84 CPY-3-O2 8.00% γ₁ [mPa · s, 20° C.]: 270 CPTP-3O2FF 4.00% CC-4-V 5.00% CCP-V-1 10.50% CCPC-33 1.50% H99: Nematic Host-Mixture

CY-3-O2 12.00% Clearing point [° C.]: 95 CY-3-O4 16.00% Δn [589 nm, 20° C.]: 0.0972 CCY-3-O2 6.50% ε_(∥) [1 kHz, 20° C.]: 3.6 CCY-3-O3 6.50% ε_(⊥) [1 kHz, 20° C.]: 7.6 CCY-4-O2 6.50% Δε [1 kHz, 20° C.]: −4.0 CCY-5-O2 6.00% K₁ [pN, 20° C.]: 14.9 CPY-2-O2 6.00% K₃ [pN, 20° C.]: 17.0 CPY-3-O2 5.50% V₀ [pN, 20° C.]: 2.17 CC-4-V 15.00% γ₁ [mPa · s, 20° C.]: 180 CCP-V-1 10.00% CCP-V2-1 10.00% stabilized with 0.03% of

H100: Nematic Host-Mixture

CY-3-O2 11.00% Clearing point [° C.]: 95 CY-3-O4 16.00% Δn [589 nm, 20° C.]: 0.1121 CCY-3-O2 6.50% ε_(∥) [1 kHz, 20° C.]: 3.7 CCY-3-O3 6.00% ε_(⊥) [1 kHz, 20° C.]: 7.7 CCY-4-O2 6.00% Δε [1 kHz, 20° C.]: −4.0 CPY-2-O2 8.00% K₁ [pN, 20° C.]: 14.8 CPY-3-O2 8.00% K₃ [pN, 20° C.]: 16.2 CPTP-3O2FF 5.00% V₀ [pN, 20° C.]: 2.13 CC-4-V 16.00% γ₁ [mPa · s, 20° C.]: 179 CCP-V-1 12.00% BCH-32 5.50% H101: Nematic Host-Mixture

CY-3-O2 3.50% Clearing point [° C.]: 102.5 CY-3-O4 16.00% Δn [589 nm, 20° C.]: 0.1112 CY-5-O2 8.75% ε_(∥) [1 kHz, 20° C.]: 3.8 CCY-3-O2 6.00% ε_(⊥) [1 kHz, 20° C.]: 8.8 CCY-3-O3 6.00% Δε [1 kHz, 20° C.]: −5.0 CCY-4-O2 6.00% K₁ [pN, 20° C.]: 15.0 CCY-5-O2 6.00% K₃ [pN, 20° C.]: 18.7 CPY-2-O2 8.00% V₀ [pN, 20° C.]: 2.04 CPY-3-O2 8.50% γ₁ [mPa · s, 20° C.]: 280 CC-4-V 3.00% CCP-V-1 7.25% CCP-V2-1 3.25% CCPC-33 2.75% CY-5-O4 6.50% CC-5-V 3.50% CCPC-34 2.00% CPTP-301 1.75% PTP-102 1.25% H102: Nematic Host-Mixture

CCY-5-O2 5.25% Clearing point [° C.]: 102 CPY-2-O2 11.75% Δn [589 nm, 20° C.]: 0.1133 CPY-3-O2 11.75% ε_(∥) [1 kHz, 20° C.]: 4.1 CC-5-V 3.00% ε_(⊥) [1 kHz, 20° C.]: 10.5 CCPC-33 1.50% Δε [1 kHz, 20° C.]: −6.4 CCPC-34 1.50% K₁ [pN, 20° C.]: 15.4 CCPC-35 1.00% K₃ [pN, 20° C.]: 18.8 CY-3-O2 8.50% V₀ [pN, 20° C.]: 1.81 CY-3-O4 23.00% γ₁ [mPa · s, 20° C.]: 367 CCY-3-O2 7.25% CCY-3-O3 6.75% CCY-4-O2 6.75% CY-5-O4 4.50% CCY-3-1 4.00% CCP-V-1 2.00% CBC-33F 1.50% H103: Nematic Host-Mixture

CY-3-O2 6.00% Clearing point [° C.]: 102 CY-3-O4 14.00% Δn [589 nm, 20° C.]: 0.0898 CCY-3-O2 4.00% ε_(∥) [1 kHz, 20° C.]: 3.1 CCY-3-O3 4.00% ε_(⊥) [1 kHz, 20° C.]: 5.3 CPY-2-O2 9.00% Δε [1 kHz, 20° C.]: −2.1 CCH-301 5.00% K₁ [pN, 20° C.]: 16.7 CC-3-V1 8.00% K₃ [pN, 20° C.]: 18.3 CC-5-V 13.00% V₀ [pN, 20° C.]: 3.11 CCP-V-1 13.00% γ₁ [mPa · s, 20° C.]: 133 CCP-V2-1 13.00% CH-33 3.00% CH-35 3.00% CP-43 3.00% CCPC-33 2.00% H104: Nematic Host-Mixture

CY-3-O2 8.00% Clearing point [° C.]: 102 CY-3-O4 4.00% Δn [589 nm, 20° C.]: 0.1501 CY-5-O2 12.00% ε_(∥) [1 kHz, 20° C.]: 4.1 CY-5-O4 6.00% ε_(⊥) [1 kHz, 20° C.]: 10.2 CCY-3-O2 6.00% Δε [1 kHz, 20° C.]: −6.1 CCY-4-O2 6.00% K₁ [pN, 20° C.]: 15.9 CCY-5-O2 6.00% K₃ [pN, 20° C.]: 18.3 CCY-3-O3 6.00% V₀ [pN, 20° C.]: 1.83 CPY-2-O2 12.00% γ₁ [mPa · s, 20° C.]: 404 CPY-3-O2 12.00% PYP-2-3 10.00% PYP-2-4 10.00% CPTP-301 2.00% H105: Nematic Host-Mixture

CY-3-O2 2.00% Clearing point [° C.]: 100 CY-3-O4 6.00% Δn [589 nm, 20° C.]: 0.1508 CY-5-O4 2.00% ε_(||) [1 kHz, 20° C.]: 3.3 CCY-3-O2 1.50% ε_(⊥) [1 kHz, 20° C.]: 5.3 CPY-2-O2 9.00% Δε [1 kHz, 20° C.]: −1.9 CPY-3-O2 9.00% K₁ [pN, 20° C.]: 15.7 PYP-2-3 10.00% K₃ [pN, 20° C.]: 16.4 PYP-2-4 10.00% V₀ [pN, 20° C.]: 3.06 PTP-102 1.50% γ₁ [mPa · s, 20° C.]: 122 CPTP-301 5.00% CPTP-302 4.00% PCH-301 5.50% CC-4-V 14.00% CC-5-V 8.00% CCP-V-1 7.50% BCH-32 5.00% H106: Nematic Host-Mixture

CY-3-O2 17.00% Clearing point [° C.]: 101 CY-3-O4 20.00% Δn [589 nm, 20° C.]: 0.0969 CY-5-O2 5.50% ε_(||) [1 kHz, 20° C.]: 4.0 CCY-3-O2 6.50% ε_(⊥) [1 kHz, 20° C.]: 10.0 CCY-3-O3 6.50% Δε [1 kHz, 20° C.]: −6.0 CCY-4-O2 6.50% K₁ [pN, 20° C.]: 14.5 CCY-5-O2 6.50% K₃ [pN, 20° C.]: 17.3 CPY-2-O2 10.50% V₀ [pN, 20° C.]: 1.80 CCH-34 3.00% γ₁ [mPa · s, 20° C.]: 322 CH-33 3.00% CH-35 3.00% CH-43 3.00% CCPC-33 3.00% CCPC-34 3.00% CCPC-35 3.00% H107: Nematic Host-Mixture

CY-3-O2 2.40% Clearing point [° C.]: 101 CY-3-O4 18.80% Δn [589 nm, 20° C.]: 0.0970 CY-5-O2 2.40% ε_(||) [1 kHz, 20° C.]: 3.7 CCY-3-O2 7.00% ε_(⊥) [1 kHz, 20° C.]: 8.2 CCY-5-O2 7.90% Δε [1 kHz, 20° C.]: −4.5 CCY-2-1 4.90% K₁ [pN, 20° C.]: 14.8 CCY-3-1 5.30% K₃ [pN, 20° C.]: 17.6 CPY-2-O2 5.70% V₀ [pN, 20° C.]: 2.09 CCH-301 8.50% γ₁ [mPa · s, 20° C.]: 244 CH-33 0.90% CH-35 0.90% CP-33 1.20% CP-35 1.20% CCPC-33 3.00% CCPC-34 2.70% CCPC-35 0.60% CCY-3-O3 4.90% CCY-4-O2 4.90% CPY-3-O2 4.20% PYP-2-3 3.50% CCH-303 4.20% CCH-501 4.90% H108: Nematic Host-Mixture

CY-3-O2 17.00% Clearing point [° C.]: 101 CY-3-O4 20.00% Δn [589 nm, 20° C.]: 0.0969 CY-5-O2 5.50% ε_(||) [1 kHz, 20° C.]: 4.0 CCY-3-O2 6.50% ε_(⊥) [1 kHz, 20° C.]: 10.0 CCY-3-O3 6.50% Δε [1 kHz, 20° C.]: −6.0 CCY-4-O2 6.50% K₁ [pN, 20° C.]: 14.5 CCY-5-O2 6.50% K₃ [pN, 20cC]: 17.3 CPY-2-O2 10.50% V₀ [pN, 20° C.]: 1.80 CCH-34 3.00% γ₁ [mPa · s, 20° C.]: 322 CH-33 3.00% CH-35 3.00% CH-43 3.00% CCPC-33 3.00% CCPC-34 3.00% CCPC-35 3.00% H109: Nematic Host-Mixture

CY-3-O2 16.00% Clearing point [° C.]: 101 CY-3-O4 20.00% Δn [589 nm, 20° C.]: 0.0953 CCY-3-O2 5.00% ε_(||) [1 kHz, 20° C.]: 3.9 CCY-3-O3 5.00% ε_(⊥) [1 kHz, 20° C.]: 9.4 CCY-4-O2 5.00% Δε [1 kHz, 20° C.]: −5.5 CCY-5-O2 5.00% K₁ [pN, 20° C.]: 16.2 CLY-2-O4 5.00% K₃ [pN, 20° C.]: 17.2 CLY-3-O2 5.00% V₀ [pN, 20° C.]: 1.85 CLY-3-O3 5.00% γ₁ [mPa · s, 20° C.]: 276 CPY-2-O2 5.00% CC-5-V 9.00% CH-33 3.00% CH-35 3.00% CP-33 3.00% CCPC-33 3.00% CCPC-34 3.00% H110: Nematic Host-Mixture

CY-3-O2 8.00% Clearing point [° C.]: 100 CY-3-O4 15.00% Δn [589 nm, 20° C.]: 0.0948 CY-5-O2 8.00% ε_(||) [1 kHz, 20° C.]: 3.9 CY-5-O4 10.00% ε_(⊥) [1 kHz, 20° C.]: 9.2 CCY-3-O2 6.00% Δε [1 kHz, 20° C.]: −5.3 CCY-3-O3 6.00% K₁ [pN, 20° C.]: 14.6 CCY-4-O2 6.00% K₃ [pN, 20° C.]: 17.3 CCY-5-O2 6.00% V₀ [pN, 20° C.]: 1.90 CPY-2-O2 10.00% γ₁ [mPa · s, 20° C.]: 298 CC-5-V 7.00% CH-33 3.00% CH-35 3.00% CP-33 3.00% CCPC-33 3.00% CCPC-34 3.00% CCPC-35 3.00% H111: Nematic Host-Mixture

CY-3-O2 9.00% Clearing point [° C.]: 106 CY-3-O4 9.00% Δn [589 nm, 20° C.]: 0.1077 CY-5-O2 12.00% ε_(||) [1 kHz, 20° C.]: 3.9 CY-5-O4 11.00% ε_(⊥) [1 kHz, 20° C.]: 9.5 CCY-3-O2 6.00% Δε [1 kHz, 20° C.]: −5.6 CCY-3-O3 6.00% K₁ [pN, 20° C.]: 15.8 CCY-4-O2 6.00% K₃ [pN, 20° C.]: 19.4 CCY-5-O2 6.00% V₀ [pN, 20° C.]: 1.96 CPY-2-O2 8.00% γ₁ [mPa · s, 20° C.]: 341 CPY-3-O2 7.00% CCP-V-1 11.00% CCPC-33 3.00% CCPC-34 3.00% CCPC-35 3.00% H112: Nematic Host-Mixture

CY-3-O2 8.00% Clearing point [° C.]: 98 CY-3-O4 17.00% Δn [589 nm, 20° C.]: 0.0914 CY-5-O2 8.00% ε_(||) [1 kHz, 20° C.]: 3.8 CCY-3-O2 8.00% ε_(⊥) [1 kHz, 20° C.]: 8.9 CCY-3-O3 8.00% Δε [1 kHz, 20° C.]: −5.1 CCY-4-O2 8.00% K₁ [pN, 20° C.]: 15.5 CCY-5-O2 8.00% K₃ [pN, 20° C.]: 16.8 CPY-2-O2 8.00% V₀ [pN, 20° C.]: 1.92 CCH-301 3.00% γ₁ [mPa · s, 20° C.]: 256 CC-5-V 10.00% CH-33 3.00% CH-35 3.00% CP-33 3.00% CP-35 2.00% CCPC-33 3.00% H113: Nematic Host-Mixture

CY-3-O2 7.00% Clearing point [° C.]: 105 CY-3-O4 16.00% Δn [589 nm, 20° C.]: 0.1024 CCY-3-O2 6.00% ε_(||) [1 kHz, 20° C.]: 3.4 CCY-3-O3 6.00% ε_(⊥) [1 kHz, 20° C.]: 6.6 CCY-4-O2 6.00% Δε [1 kHz, 20° C.]: −3.2 CPY-2-O2 7.50% K₁ [pN, 20° C.]: 18.4 CPY-3-O2 7.50% K₃ [pN, 20° C.]: 21.2 CC-3-V1 8.00% V₀ [pN, 20° C.]: 2.79 CC-S-V 9.00% γ₁ [mPa · s, 20° C.]: 171 CCP-V-1 13.50% CCP-V2-1 13.50% H114: Nematic Host-Mixture

CY-3-O2 9.00% Clearing point [° C.]: 106 CY-3-O4 9.00% Δn [589 nm, 20° C.]: 0.1077 CY-5-O2 12.00% ε_(||) [1 kHz, 20° C.]: 3.9 CY-5-O4 11.00% ε_(⊥) [1 kHz, 20° C.]: 9.5 CCY-3-O2 6.00% Δε [1 kHz, 20° C.]: −5.6 CCY-3-O3 6.00% K₁ [pN, 20° C.]: 15.8 CCY-4-O2 6.00% K₃ [pN, 20° C.]: 19.4 CCY-5-O2 6.00% V₀ [pN, 20° C.]: 1.96 CPY-2-O2 8.00% γ₁ [mPa · s, 20° C.]: 341 CPY-3-O2 7.00% CCP-V-1 11.00% CCPC-33 3.00% CCPC-34 3.00% CCPC-35 3.00% H115: Nematic Host-Mixture

CY-3-O2 4.00% Clearing point [20° C.]: 100 CY-3-O4 12.50% Δn [589 nm, 20° C.]: 0.1566 CCY-3-O2 3.50% ε_(||) [1 kHz, 20° C.]: 3.6 CPY-2-O2 12.00% ε_(⊥) [1 kHz, 20° C.]: 6.6 CPY-3-O2 12.00% Δε [1 kHz, 20° C.]: −3.0 PYP-2-3 11.00% K₁ [pN, 20° C.]: 15.5 PYP-2-4 11.00% K₃ [pN, 20° C.]: 17.1 CPTP-301 5.00% V₀ [pN, 20° C.]: 2.50 CPTP-302 5.00% γ₁ [mPa · s, 20° C.]: 202 CC-4-V 14.00% CC-5-V 7.00% BCH-32 3.00% H116: Nematic Host-Mixture

CY-3-O2 8.00% Clearing point [° C.]: 98 CY-3-O4 17.00% Δn [589 nm, 20° C.]: 0.0914 CY-5-O2 8.00% ε_(||) [1 kHz, 20° C.]: 3.8 CCY-3-O2 8.00% ε_(⊥) [1 kHz, 20° C.]: 8.9 CCY-3-O3 8.00% Δε [1 kHz, 20° C.]: −5.1 CCY-4-O2 8.00% K₁ [pN, 20° C.]: 15.5 CCY-5-O2 8.00% K₃ [pN, 20° C.]: 16.8 CPY-2-O2 8.00% V₀ [pN, 20° C.]: 1.92 CCH-301 3.00% γ₁ [mPa · s, 20° C.]: 256 CC-5-V 10.00% CH-33 3.00% CH-35 3.00% CP-33 3.00% CP-35 2.00% CCPC-33 3.00% H117: Nematic Host-Mixture

CY-3-O2 2.40% Clearing point [° C.]: 101 CY-3-O4 18.80% Δn [589 nm, 20° C.]: 0.0970 CY-5-O2 2.40% ε_(||) [1 kHz, 20° C.]: 3.7 CCY-3-O2 7.00% ε_(⊥) [1 kHz, 20° C.]: 8.2 CCY-5-O2 7.90% Δε [1 kHz, 20° C.]: −4.5 CCY-2-1 4.90% K₁ [pN, 20° C.]: 14.8 CCY-3-1 5.30% K₃ [pN, 20° C.]: 17.6 CPY-2-O2 5.70% V₀ [pN, 20° C.]: 2.09 CCH-301 8.50% γ₁ [mPa · s, 20° C.]: 244 CH-33 0.90% CH-35 0.90% CP-33 1.20% CP-35 1.20% CCPC-33 3.00% CCPC-34 2.70% CCPC-35 0.60% CCY-3-O3 4.90% CCY-4-O2 4.90% CPY-3-O2 4.20% PYP-2-3 3.50% CCH-303 4.20% CCH-501 4.90% H118: Nematic Host-Mixture

CY-3-O2 6.00% Clearing point [° C.]: 101 CY-3-O4 13.00% Δn [589 nm, 20° C.]: 0.1483 CCY-3-O2 6.00% ε_(||) [1 kHz, 20° C.]: 3.6 CCY-3-O3 5.00% ε_(⊥) [1 kHz, 20° C.]: 7.0 CPY-2-O2 4.00% Δε [1 kHz, 20° C.]: −3.4 CC-4-V 14.00% K₁ [pN, 20° C.]: 16.6 CCP-V-1 10.00% K₃ [pN, 20° C.]: 18.8 CCP-V2-1 11.00% V₀ [pN, 20° C.]: 2.47 CPTP-3-1 5.00% γ₁ [mPa · s, 20° C.]: PTP-3O2FF 8.00% PTP-5O2FF 8.00% CPTP-3O2FF 5.00% CPTP-5O2FF 5.00% H119: Nematic Host-Mixture

CY-3-O2 10.00% Clearing point [20° C.]: 100 CY-3-O4 20.00% Δn [589 nm, 20° C.]: 0.0865 CY-5-O4 20.00% ε_(||) [1 kHz, 20° C.]: 3.9 CCY-3-O2 6.00% ε_(⊥) [1 kHz, 20° C.]: 9.3 CCY-3-O3 6.00% Δε [1 kHz, 20° C.]: −5.4 CCY-4-O2 6.00% K₁ [pN, 20° C.]: 15.6 CCY-5-O2 6.00% K₃ [pN, 20° C.]: 16.6 CH-33 3.00% V₀ [pN, 20° C.]: 1.84 CH-35 3.50% γ₁ [mPa · s, 20° C.]: 347 CH-43 3.50% CH-45 3.50% CCPC-33 4.00% CCPC-34 4.50% CCPC-35 4.00% H120: Nematic Host-Mixture

CY-3-O2 3.00% Clearing point [° C.]: 102 CY-3-O4 10.00% Δn [589 nm, 20° C.]: 0.1602 CCY-3-O2 6.00% ε_(||) [1 kHz, 20° C.]: 3.8 CCY-3-O3 6.00% ε_(⊥) [1 kHz, 20° C.]: 7.8 CCY-4-O2 6.00% Δε [1 kHz, 20° C.]: −4.0 CPY-2-O2 5.00% K₁ [pN, 20° C.]: 16.8 CC-4-V 14.00% K₃ [pN, 20° C.]: 19.3 CCP-V-1 5.00% V₀ [pN, 20° C.]: 2.32 CCP-V2-1 10.00% γ₁ [mPa · s, 20° C.]: 216 PPTUI-3-2 3.00% PTP-3O2FF 11.00% PTP-5O2FF 11.00% CPTP-3O2FF 5.00% CPTP-5O2FF 5.00% H121: Nematic Host-Mixture

CY-3-O2 5.00% Clearing point [° C.]: 102 CY-3-O4 15.00% Δn [589 nm, 20° C.]: 0.2503 CCY-3-O2 6.00% ε_(||) [1 kHz, 20° C.]: 4.3 CCY-3-O3 6.00% ε_(⊥) [1 kHz, 20° C.]: 8.3 CPY-2-O2 3.00% Δε [1 kHz, 20° C.]: −4.0 PTP-102 5.00% K₁ [pN, 20° C.]: 19.5 PPTUI-3-2 15.00% K₃ [pN, 20° C.]: 24.0 PPTUI-3-4 11.00% V₀ [pN, 20° C.]: 2.57 PTP-3O2FF 12.00% γ₁ [mPa · s, 20° C.]: 392 PTP-5O2FF 12.00% CPTP-3O2FF 5.00% CPTP-5O2FF 5.00% H122: Nematic Host-Mixture

CY-3-O4 12.00% Clearing point [° C.]: 91 PY-3-O2 6.50% Δn [589 nm, 20° C.]: 0.2100 CCY-3-O2 2.00% ε_(||) [1 kHz, 20° C.]: 4.0 CPY-2-O2 3.50% ε_(⊥) [1 kHz, 20° C.]: 7.1 CC-4-V 13.50% Δε [1 kHz, 20° C.]: −3.1 CC-5-V 4.00% K₁ [pN, 20° C.]: 15.3 PPTUI-3-2 15.00% K₃ [pN, 20° C.]: 19.3 PPTUI-3-4 5.50% V₀ [pN, 20° C.]: 2.64 PTP-3O2FF 12.00% γ₁ [mPa · s, 20° C.]: 211 PTP-5O2FF 12.00% CPTP-3O2FF 5.00% CPTP-5O2FF 5.00% CCPC-33 4.00% H123: Nematic Host-Mixture

D-302FF 8.00% Clearing point [° C.]: 102 D-402FF 8.00% Δn [589 nm, 20° C.]: 0.14780 D-502FF 8.00% ε_(||) [1 kHz, 20° C.]: 3.4 PCH-301 18.00% ε_(⊥) [1 kHz, 20° C.]: 5.1 PCH-302 15.00% Δε [1 kHz, 20° C.]: −1.7 PCH-304 4.00% PTP-102 4.00% PTP-201 4.00% CPTP-301 6.00% CPTP-302 6.00% CPTP-303 7.00% CCPC-33 4.00% CCPC-34 4.00% CCPC-35 4.00% H124: Nematic Host-Mixture

D-302FF 15.00% Clearing point [° C.]: 109 D-402FF 15.00% Δn [589 nm, 20° C.]: 0.1727 D-502FF 15.00% ε_(||) [1 kHz, 20° C.]: 5.2 CP-302FF 5.00% ε_(⊥) [1 kHz, 20° C.]: 13.2 CP-402FF 5.00% Δε [1 kHz, 20° C.]: −8.0 CP-502FF 5.00% K₁ [pN, 20° C.]: 15.6 PTP-3O2FF 10.00% K₃ [pN, 20° C.]: 22.8 PTP-5O2FF 10.00% CPTP-3O2FF 10.00% CPTP-5O2FF 10.00% H125: Nematic Host-Mixture

D-302FF 7.00% Clearing point [° C.]: 85 D-402FF 7.00% Δn [589 nm, 20° C.]: 0.1640 D-502FF 7.00% ε_(||) [1 kHz, 20° C.]: 3.7 PTP-3O2FF 10.00% ε_(⊥) [1 kHz, 20° C.]: 6.4 PTP-5O2FF 10.00% Δε [1 kHz, 20° C.]: −2.7 CPTP-301 5.00% CPTP-302 5.00% CPTP-303 5.00% PCH-301 19.00% PCH-302 17.00% CBC-33F 5.00% CBC-53F 3.00% H126: Nematic Host-Mixture

CCPC-33 1.50% Clearing point [° C.]: 91 CCPC-34 1.50% Δn [589 nm, 20° C.]: 0.1029 CCPC-35 1.50% ε_(||) [1 kHz, 20° C.]: 3.5 CCY-2-1 4.50% ε_(⊥) [1 kHz, 20° C.]: 7.2 CCY-3-1 3.50% Δε [1 kHz, 20° C.]: −3.7 CCY-3-O2 7.00% K₁ [pN, 20° C.]: 15.5 CCY-3-O3 8.00% K₃ [pN, 20° C.]: 15.2 CCY-4-O2 7.00% V₀ [pN, 20° C.]: 2.21 CPY-2-O2 6.00% γ₁ [mPa · s, 20° C.]: 231 CPY-3-O2 6.00% CY-3-O4 12.00% CY-5-O4 12.00% PCH-53 10.50% CCH-34 5.50% CCOC-3-3 2.00% CCOC-4-3 2.00% CCOC-3-5 2.00% CBC-33 1.50% PP-1-2V1 6.00% H127: Nematic Host-Mixture

CY-5-O2 7.00% Clearing point [° C.]: 95 CPY-2-O2 11.00% Δn [589 nm, 20° C.]: 0.1268 CPY-3-O2 10.00% ε_(||) [1 kHz, 20° C.]: 4.0 PYP-2-3 6.00% ε_(⊥) [1 kHz, 20° C.]: 7.7 PYP-2-4 7.00% Δε [1 kHz, 20° C.]: −3.7 CC-4-V 17.00% K₁ [pN, 20° C.]: 15.5 CC-3-V1 9.00% K₃ [pN, 20° C.]: 15.2.0 CCH-34 5.00% V₀ [pN, 20° C.]: 2.15 CPYP-3-2 5.00% γ₁ [mPa · s, 20° C.]: 155 CPYP-2-1 5.00% CK-3-F 9.00% CK-5-F 9.00% H128: Nematic Host-Mixture

CY-3-O4 18.00% Clearing point [° C.]: 96 CY-5-O2 10.00% Δn [589 nm, 20° C.]: 0.1275 CCY-4-O2 10.00% ε_(||) [1 kHz, 20° C.]: 4.0 CCY-3-O3 10.00% ε_(⊥) [1 kHz, 20° C.]: 9.1 CPY-2-O2 11.00% Δε [1 kHz, 20° C.]: −5.1 CPY-3-O2 12.00% K₁ [pN, 20° C.]: 14.4 PYP-2-3 5.00% K₃ [pN, 20° C.]: 15.6 PYP-2-4 4.00% V₀ [pN, 20° C.]: 1.84 CC-4-V 13.00% γ₁ [mPa · s, 20° C.]: 253 CPYP-3-2 7.00% H129: Nematic Host-Mixture

CY-3-O2 3.00% Clearing point [° C.]: 102 CY-3-O4 10.00% Δn [589 nm, 20° C.]: 0.1602 CCY-3-O2 6.00% ε_(||) [1 kHz, 20° C.]: 3.8 CCY-3-O3 6.00% ε_(⊥) [1 kHz, 20° C.]: 7.8 CCY-4-O2 6.00% Δε [1 kHz, 20° C.]: −4.0 CPY-2-O2 5.00% K₁ [pN, 20° C.]: 16.8 CC-4-V 14.00% K₃ [pN, 20° C.]: 19.3 CCP-V-1 5.00% V₀ [pN, 20° C.]: 2.32 CCP-V2-1 10.00% LTS [bulk, −20° C.]: >1000 h PPTUI-3-2 3.00% PTP-302FF 11.00% PTP-502FF 11.00% CPTP-302FF 5.00% CPTP-502FF 5.00% H130: Nematic Host-Mixture

CY-3-O2 10.00% Clearing point [° C.]: 100 CY-3-O4 20.00% Δn [589 nm, 20° C.]: 0.0865 CY-5-O4 20.00% ε_(||) [1 kHz, 20° C.]: 3.9 CCY-3-O2 6.00% ε_(⊥) [1 kHz, 20° C.]: 9.3 CCY-3-O3 6.00% Δε [1 kHz, 20° C.]: −5.4 CCY-4-O2 6.00% K₁ [pN, 20° C.]: 15.6 CCY-5-O2 6.00% K₃ [pN, 20° C.]: 16.6 CH-33 3.00% V₀ [pN, 20° C.]: 1.84 CH-35 3.50% CH-43 3.50% CH-45 3.50% CCPC-33 4.00% CCPC-34 4.50% CCPC-35 4.00% H131: Nematic Host-Mixture

Y-4O-O4 4.50% Clearing point [° C.]: 100 PYP-2-3 2.00% Δn [589 nm, 20° C.]: 0.1716 CC-3-V 25.00% ε_(||) [1 kHz, 20° C.]: 3.4 CC-4-V 10.00% ε_(⊥) [1 kHz, 20° C.]: 4.9 CCP-V-1 14.00% Δε [1 kHz, 20° C.]: −1.5 PTP-302FF 10.00% K₁ [pN, 20° C.]: 15.2 CPTP-302FF 10.00% K₃ [pN, 20° C.]: 18.5 CPTP-502FF 10.00% V₀ [pN, 20° C.]: 3.76 PPTUI-3-2 14.50% LTS [bulk, −20° C.]: >1000 h H132: Nematic Host-Mixture

Y-4O-O4 6.00% Clearing point [° C.]: 110 CC-3-V 25.00% Δn [589 nm, 20° C.]: 0.1745 CCP-V-1 13.00% ε_(||) [1 kHz, 20° C.]: 3.5 CCP-V2-1 12.50% ε_(⊥) [1 kHz, 20° C.]: 5.1 PTP-302FF 10.00% Δε [1 kHz, 20° C.]: −1.6 CPTP-302FF 10.00% K₁ [pN, 20° C.]: 17.6 CPTP-502FF 10.00% K₃ [pN, 20° C.]: 21.2 PPTUI-3-2 13.50% V₀ [pN, 20° C.]: 3.79 LTS [bulk, −40° C.]: >1000 h H133: Nematic Host-Mixture

Y-4O-O4 12.50% Clearing point [° C.]: 105 CY-3-O4 5.00% Δn [589 nm, 20° C.]: 0.0868 CY-5-O4 18.00% ε_(||) [1 kHz, 20° C.]: 4.2 CCY-3-O1 4.00% ε_(⊥) [1 kHz, 20° C.]: 9.6 CCY-3-O2 6.00% Δε [1 kHz, 20° C.]: −5.4 CCY-3-O3 6.00% K₁ [pN, 20° C.]: 16.7 CCY-4-O2 6.00% K₃ [pN, 20° C.]: 16.5 CCY-5-O2 6.00% V₀ [pN, 20° C.]: 1.85 CPY-3-O2 4.50% CH-33 4.00% CH-35 4.00% CH-43 4.00% CH-45 4.00% CCOC-3-3 2.00% CCOC-4-3 2.00% CCPC-33 4.00% CCPC-34 4.00% CCPC-35 4.00% H134: Nematic Host-Mixture

CY-3-O2 5.00% Clearing point [° C.]: 102 CY-3-O4 15.00% Δn [589 nm, 20° C.]: 0.2503 CCY-3-O2 6.00% ε_(||) [1 kHz, 20° C.]: 4.3 CCY-3-O3 6.00% ε_(⊥) [1 kHz, 20° C.]: 8.3 CPY-2-O2 3.00% Δε [1 kHz, 20° C.]: −4.0 PTP-102 5.00% K₁ [pN, 20° C.]: 19.5 PPTUI-3-2 15.00% K₃ [pN, 20° C.]: 24.0 PPTUI-3-4 11.00% V₀ [pN, 20° C.]: 2.57 PTP-302FF 12.00% γ₁ [mPa · s, 20° C.]: PTP-502FF 12.00% LTS [bulk, −20° C.]: >1000 h CPTP-302FF 5.00% CPTP-502FF 5.00%

Example M1-a

The compound of the formula I-2a-1 (4%) is added to the nematic host mixture H1. The resulting mixture is homogenised and filled into an “alignment-free” test cell (cell thickness d˜4.0 μm, ITO coating on both sides (structured ITO in case of a multi-domain switching), no alignment layer and no passivation layer).

The LC-mixture shows a spontaneous homeotropic (vertical) orientation with respect to the surface of the substrates. The orientation is stable until the clearing point and the resulting VA-cell can be reversibly switched. Crossed polarizers are needed to display the switching.

By using additives like the compound of the formula I-2a-1, no alignment layer (e.g. no Pl coating) is required anymore for PVA, MVA, and other analogue display technologies with vertically aligned liquid crystals.

Example M1-b

The compound of the formula I-2a-1 (2%) is added to the nematic host mixture H1. The resulting mixture is homogenised and filled into an “alignment-free” test cell (cell thickness d˜4.0 μm, ITO coating on both sides (structured ITO in case of a multi-domain switching), no alignment layer and no passivation layer).

The LC-mixture shows a spontaneous homeotropic (vertical) orientation with respect to the surface of the substrates. The orientation is stable until the clearing point and the resulting VA-cell can be reversibly switched. Crossed polarizers are needed to display the switching.

By using additives like the compound of the formula I-2a-1, no alignment layer (e.g. no Pl coating) is required anymore for PVA, MVA, and other analogue display technologies with vertically aligned liquid crystals.

Example 1P a): Polymer Stabilization of the LC Mixture of Example M1-a

The polymerizable derivative RM-1 (0.3%) is added to the nematic LC-mixture of Example M1-a. The resulting mixture is homogenised and filled into an “alignment-free” test cell (cell thickness d˜4.0 m, ITO coating on both sides (structured ITO in case of a multi-domain switching), no alignment layer and no passivation layer).

The LC-mixture shows a spontaneous homeotropic (vertical) orientation, with respect to the surface of the substrates. The resulting VA-cell is treated with UV-light (15 min, 100 mW/cm²) after having applied to the cell a voltage higher than the optical threshold. The polymerizable derivative polymerizes and, as a consequence, the homeotropic self-orientation is stabilized and the tilt of the mixture is tuned. The resulting PSA-VA-cell can be reversibly switched even at high temperatures. The switching times are reduced, compared to the not polymerized system.

Additives like Irganox 1076 (BASF) may be added (e.g. 0.001%) for preventing spontaneous polymerization. UV-cut filter may be used during polymerization for preventing damage of the mixtures (e.g. 340 nm cut-off-filter).

By using additives like the compound of the formula I-2a-1 in combination with RM-1, no alignment layer is required anymore for PSA, PS-VA, and other analogue display technologies with vertically aligned liquid crystals.

Example 1P b): Polymer Stabilization of the LC Mixture of Example M1

The polymerizable derivative RM-41 (0.3%) is added to the nematic LC-mixture of Example M1-a. The resulting mixture is homogenised and filled into an “alignment-free” test cell (cell thickness d˜4.0 μm, ITO coating on both sides (structured ITO in case of a multi-domain switching), no alignment layer and no passivation layer). The resulting cell is treated according to Example 1P a) and similar results are obtained.

By using additives like the compound of the formula I-2a-1 in combination with RM-41, no alignment layer is required anymore for PSA, PS-VA, and other analogue display technologies with vertically aligned liquid crystals.

Examples M2 to M134 and 2P a) to 134P b)

The compound of the formula I-2a-1 (4%) is added to the nematic host mixtures H2-H134. The resulting mixtures M2 to M134 are homogenised and filled into an “alignment-free” test cell (cell thickness d˜4.0 μm, ITO coating on both sides (structured ITO in case of a multi-domain switching), no alignment layer and no passivation layer).

The LC-mixtures show a spontaneous homeotropic (vertical) orientation with respect to the surface of the substrates. The orientation is stable until the clearing point and the resulting VA-cell can be reversibly switched. Crossed polarizers are needed to display the switching.

The polymerizable derivative RM-1 (0.3%) or RM-41 (0.3%) is added to the nematic LC mixtures of Examples M2-M134. The resulting mixtures are homogenised and filled into an “alignment-free” test cell (cell thickness d˜4.0 μm, ITO coating on both sides (structured ITO in case of a multi-domain switching), no alignment layer and no passivation layer). The resulting cell is treated according to example 1P a). Equivalent results are obtained.

Examples 1P c) to 134 P f)

Analogues mixtures like 1P a) to 134 P b) are obtained by mixing the nematic LC mixtures M1 to M134 with RM35 (0.3%), RM43 (0.3%), RM55 (0.3%) or RM83 (0.3%), obtaining mixtures 1P c) to 134 P f). These mixtures are treated according to Example 1P a). In all cases an improvement of the switching times is found.

Example M135

To the following nematic host mixture

Y-4O-O4 12.50% Clearing point [° C.]: 105 CY-3-O4 5.00% Δn [589 nm, 20° C.]: 0.0868 CY-5-O4 18.00% Δε [1 kHz, 20° C.]: −5.4 CCY-3-O1 4.00% ε_(||) [1 kHz, 20° C.]: 4.2 CCY-3-O2 6.00% CCY-3-O3 6.00% CCY-4-O2 6.00% CCY-5-O2 6.00% CPY-3-O2 4.50% CH-33 4.00% CH-35 4.00% CH-43 4.00% CH-45 4.00% CCOC-3-3 2.00% CCOC-4-3 2.00% CCPC-33 4.00% CCPC-34 4.00% CCPC-35 4.00% is added 0.4% of the compound of the formula

Example M136

To the following nematic host mixture

CY-3-O4 16.00% Clearing point [° C.]: 109 CCY-3-O1 4.00% Δn [589 nm, 20° C.]: 0.0854 CCY-3-O2 6.00% Δε [1 kHz, 20° C.]: −5.3 CCY-3-O3 6.00% ε_(||) [1 kHz, 20° C.]: 4.3 CCY-4-O2 6.00% CCY-5-O2 5.00% CCH-301 6.00% CC-4-V 15.00% CC-3-V1 6.00% CCP-V-1 13.00% CCP-V2-1 13.00% CCPC-33 4.00% is added 0.4% of the compound of the formula

Example M137

To the following nematic host mixture

Y-4-O-O4 10.00% Clearing point [° C.]: 107 CY-3-O2 7.00% Δn [589 nm, 20° C.]: 0.1104 CY-3-O4 15.00% Δε [1 kHz, 20° C.]: −6.0 CCY-3-O1 4.00% ε_(||) [1 kHz, 20° C.]: 4.3 CCY-3-O2 6.00% CCY-3-O3 6.00% CCY-4-O2 6.00% CCY-5-O2 6.00% CPY-3-O2 9.00% CPY-3-O2 9.00% CCP-V-1 8.50% CCPC-33 4.00% CCPC-34 4.00% CCPC-35 3.50% CBC-33F 2.00% is added 0.4% of the compound of the formula

Example M138

To the following nematic host mixture

Y-4O-O4 3.00% Clearing point [° C.]: 108 CY-3-O4 8.00% Δn [589 nm, 20° C.]: 0.1096 CCY-3-O1 4.00% Δε [1 kHz, 20° C.]: −2.4 CCY-3-O2 6.00% ε_(||) [1 kHz, 20° C.]: 3.2 CCY-3-O3 6.00% CPY-2-O2 8.00% CPY-3-O2 8.00% PCH-301 5.50% CC-4-V 15.00% CC-3-V1 5.50% CCP-V-1 13.00% CCP-V2-1 13.00% CPTP-301 5.00% is added 0.4% of the compound of the formula

Example M139 Multi Bottle System

The multi bottle bottle system is prepared by mixing of

25% of M135

25% of M136

25% of M137

25% of M138

and has the following composition:

CBC-33F  0.48% Clearing point [° C.]: 100 CC-3-V1  2.76% Δn [589 nm, 20° C.]: 0.0993 CC-4-V  7.20% ε_(||) [1 kHz, 20° C.]: 3.8 CCH-301  1.44% ε_(⊥) [1 kHz, 20° C.]: 7.6 CCOC-3-3  0.48% Δε [1 kHz, 20° C.]: −3.8 CCOC-4-3  0.48% K₁ [pN, 20° C.]: 15.3 CCP-V-1  8.28% K₃ [pN, 20° C.]: 17.8 CCP-V2-1  6.24% V₀ [pN, 20° C.]: 2.29 CCPC-33  2.88% CCPC-34  1.92% CCPC-35  1.80% CCY-3-O1  3.84% CCY-3-O2  5.76% CCY-3-O3  5.76% CCY-4-O2  4.32% CCY-5-O2  4.08% CH-33  0.96% CH-35  0.96% CH-43  0.96% CH-45  0.96% CPTP-301  1.20% CPY-2-O2  4.08% CPY-3-O2  5.16% CY-3-O2  1.68% CY-3-O4 10.56% CY-5-O4  4.32% PCH-301  1.32% Y-4O-O4  6.12%

 4.00%

The mixtures of Examples M135 to M139 are highly suitable for PM (passive matrix)-VA applications.

The preceding examples can be repeated with similar success by substituting the generically or specifically described reactants and/or operating conditions of this invention for those used in the preceding examples.

From the foregoing description, one skilled in the art can easily ascertain the essential characteristics of this invention and, without departing from the spirit and scope thereof, can make various changes and modifications of the invention to adapt it to various usages and conditions. 

The invention claimed is:
 1. A liquid-crystalline medium comprising a mixture of polar compounds, including in said mixture at least one compound of formula I,

in which R¹ denotes an alkyl or alkoxy radical having 1 to 15 C atoms, where, in addition, one or more CH₂ groups in these radicals may each be replaced, independently of one another, by —C≡C—, —CF₂O—, —CH═CH—,

—O—, —CO—O—, —O—CO— in such a way that O atoms are not linked directly to one another, and in which, in addition, one or more H atoms may be replaced by halogen, L¹, L² and L³ each, independently of one another, denote H, F, Cl, CF₃, CHF₂ or alkyl with 1-5 carbon atoms, preferably F or alkyl, and m denotes 0, 1, 2, 3, 4, 5 or 6, and at least one compound of the formulae I-A, I-B, I-G OR I-J,

in which R¹* and R² each, independently of one another, denote an alkyl or alkoxy radical having 1 to 15 C atoms, where, in addition, one or more CH₂ groups in these radicals may each be replaced, independently of one another, by —C≡C—, —CF₂O—, —CH═CH—,

—O—, —CO—O—, —O—CO— in such a way that O atoms are not linked directly to one another, and in which, in addition, one or more H atoms may be replaced by halogen, a 0 or 1, and L¹ and L² each, independently of one another, denote H, F, Cl, CF₃ or CHF₂.
 2. The liquid-crystalline medium according to claim 1, comprising one or more compounds of formulae I-1 to I-36,


3. The liquid-crystalline medium according to claim 1, comprising one or more compounds of formulae I-1a, I-2a or I-2b,

in which alkyl denotes a straight-chain alkyl radical having 1 to 7 carbon atoms.
 4. The liquid-crystalline medium according to claim 1, comprising one or more compounds of formulae I-A-1 to I-K-1,

in which alkyl and alkyl* each, independently of one another, denote a straight-chain alkyl radical having 1-6 C atoms, and alkoxy denotes a straight-chain alkoxy radical having 1-6 C atoms, L¹ and L² each, independently of one another, denote H, F, Cl, CF₃ or CHF₂.
 5. The liquid-crystalline medium according to claim 1, additionally comprising one or more compounds of the formulae IIA to IIC,

in which R^(2A), R^(2B) and R^(2C) each, independently of one another, denote H, an alkyl or alkenyl radical having up to 15 C atoms which is unsubstituted, monosubstituted by CN or CF₃ or at least monosubstituted by halogen, where, in addition, one or more CH₂ groups in these radicals may be replaced by —O—, —S—,

—C≡C—, —CF₂O—, —OCF₂—, —OC—O— or —O—CO— in such a way that O atoms are not linked directly to one another, L¹⁻⁴ each, independently of one another, denote F or Cl, Z² and Z^(2′) each, independently of one another, denote a single bond, —CH₂CH₂—, —CH═CH—, —CF₂O—, —OCF₂—, —CH₂O—, —OCH₂—, —COO—, —OCO—, —C₂F₄—, —CF═CF—, —CH═CHCH₂O—, p denotes 1 or 2, q denotes 0 or 1, and v denotes 1 to
 6. 6. The liquid-crystalline medium according to claim 1, additionally comprising one or more compounds of formula III,

in which R³¹ and R³² each, independently of one another, denote a straight-chain alkyl, alkoxyalkyl, alkenyl, or alkoxy radical having up to 12 C atoms, and

and Z³ denotes a single bond, —CH₂CH₂—, —CH═CH—, —CF₂O—, —OCF₂—, —CH₂O—, —OCH₂—, —COO—, —OCO—, —C₂F₄—, —C₄H₉—, —CF═CF—.
 7. The liquid-crystalline medium according to claim 1, additionally comprising one or more compounds of the formulae L-1 to L-11,

in which R, R¹ and R² each, independently of one another, denote H, an alkyl or alkenyl radical having up to 15 C atoms which is unsubstituted, monosubstituted by CN or CF₃ or at least monosubstituted by halogen, where, in addition, one or more CH₂ groups in these radicals may be replaced by —O—, —S—,

—C≡C—, —CF₂O—, —OCF₂—, —OC—O— or —O—CO— in such a way that O atoms are not linked directly to one another, and alkyl denotes an alkyl radical having 1-6 C atoms, and s denotes 1 or
 2. 8. The liquid-crystalline medium according to claim 1, additionally comprising one or more compounds of formulae T-1 to T-21,

in which R denotes a straight-chain alkyl or alkoxy radical having 1-7 C atoms, and m denotes 1-6.
 9. The liquid-crystalline medium according to claim 1, additionally comprising one or more compounds of formulae O-1 to O-11,

in which R¹ and R² each, independently of one another, denote H, an alkyl or alkenyl radical having up to 15 C atoms which is unsubstituted, monosubstituted by CN or CF₃ or at least monosubstituted by halogen, where, in addition, one or more CH₂ groups in these radicals may be replaced by —O—, —S—,

—C≡C—, —CF₂O—, —OCF₂—, —OC—O— or —O—CO— in such a way that O atoms are not linked directly to one another.
 10. The liquid-crystalline medium according to claim 1, wherein the mixture contains 0.01 to 10% by weight of the compound of the formula I based on the mixture as a whole.
 11. The liquid-crystalline medium according to claim 1 additionally comprising one or more additives.
 12. The liquid-crystalline medium according to claim 1, comprising an additive that is an antioxidant, stabilizer, reactive mesogen, dopant, microparticle, nanoparticle or dyes.
 13. The liquid-crystalline medium according to claim 1, additionally comprising at least one stabilizer of the formula:


14. The liquid-crystalline medium according to claim 1, additionally comprising at least one reactive mesogen of formulae M1 to M41,

in which the individual radicals have the following meanings: P¹, P² and P³ each, independently of one another, denote a polymerizable group, Sp¹, Sp² and Sp³ each, independently of one another, denote a single bond or a spacer group, where, in addition, one or more of the radicals P¹-Sp¹-, P²—Sp²- and P³—Sp³- may denote R^(aa), with the proviso that at least one of the radicals P¹—Sp¹-, P²—Sp²- and P³-Sp³- present does not denote R^(aa), R^(aa) denotes H, F, Cl, CN or straight-chain or branched alkyl having 1 to 25 C atoms, in which, in addition, one or more non-adjacent CH₂ groups may each be replaced, independently of one another, by C(R⁰)═C(R⁰⁰)—, —C≡C—, —N(R⁰)—, —O—, —S—, —CO—, —CO—O—, —O—CO—, —O—CO—O— in such a way that O and/or S atoms are not linked directly to one another, and in which, in addition, one or more H atoms may be replaced by F, Cl, CN or P¹-Sp¹-, particularly preferably straight-chain or branched, optionally mono- or polyfluorinated alkyl, alkoxy, alkenyl, alkynyl, alkylcarbonyl, alkoxycarbonyl, alkylcarbonyloxy or alkoxycarbonyloxy having 1 to 12 C atoms (where the alkenyl and alkynyl radicals have at least two C atoms and the branched radicals have at least three C atoms), R⁰, R⁰⁰ each, independently of one another and identically or differently on each occurrence, denote H or alkyl having 1 to 12 C atoms, X¹, X² and X³ each, independently of one another, denote —CO—O—, —O—CO— or a single bond, Z¹ denotes —O—, —CO—, —C(R^(y)R^(z))— or —CF₂CF₂—, R^(y) and R^(z) each, independently of one another, denote H, F, CH₃ or CF₃, Z² denotes —CO—O—, —O—CO—, —CH₂O—, —OCH₂—, —CF₂O—, —OCF₂— or —(CH₂)_(n)—, where n is 2, 3 or 4, L on each occurrence, identically or differently, denotes F, Cl, CN or straight-chain or branched, optionally mono- or polyfluorinated alkyl, alkoxy, alkenyl, alkynyl, alkylcarbonyl, alkoxycarbonyl, alkylcarbonyloxy or alkoxycarbonyloxy having 1 to 12 C atoms, L′ and L″ each, independently of one another, denote H, F or Cl, r denotes 0, 1, 2, 3 or 4, s denotes 0, 1, 2 or 3, t denotes 0, 1 or 2, x denotes 0 or
 1. 15. The liquid-crystalline medium according to claim 1, additionally comprising at least one reactive mesogen of the formulae RM-1 to RM-98,


16. A process for the preparation of a liquid-crystalline medium according to claim 1, comprising mixing at least one compound of the formula I and at least one compound of the formulae I-A to I-K with at least one further liquid-crystalline compound, and additives are optionally added.
 17. An electro-optical display having active-matrix or passive matrix addressing, said display comprising as a dielectric, a liquid-crystalline medium according to claim
 1. 18. The electro-optical display according to claim 17 that is a VA, PM-VA, PSA, PS-VA, PALC, FFS, PS-FFS, IPS or PS-IPS display.
 19. The electro-optical display according to claim 17, operated in self-aligning VA mode.
 20. The liquid-crystalline medium according to claim 14, wherein P¹, P² or P³ is a polymerizable group having an acrylate, methacrylate, fluoroacrylate, oxetane, vinyl, vinyloxy or epoxide group, and Sp¹, Sp² or Sp³ are —(CH₂)_(p1)—, —(CH₂)_(p1)—O—, —(CH₂)_(p1)—CO—O— or —(CH₂)_(p1)—O—CO—O—, in which p1 is an integer from 1 to 12, and where the linking to the adjacent ring in the last-mentioned groups takes place via the O atom.
 21. The liquid crystalline mixture according to claim 1, further comprising


22. The liquid crystalline medium according to claim 21, comprising 